Topological and threading effects in polydisperse ring polymer solutions

被引:10
作者
Chubak, Iurii [1 ]
Likos, Christos N. [1 ]
Smrek, Jan [1 ]
机构
[1] Univ Vienna, Fac Phys, Boltzmanngasse 5, A-1090 Vienna, Austria
基金
奥地利科学基金会;
关键词
Ring polymers; coarse-graining; effective models; Monte Carlo simulation; topological potential; threading; CONFORMATIONS; SIMULATION; MELT;
D O I
10.1080/00268976.2021.1883140
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We explore effective interactions in dilute polydisperse ring polymer solutions. Based on a topological and threading analysis, we deduce the steric, topological and threading contributions to the effective potentials for differently sized rings. Additionally, we quantify the contribution of topological constraints for different asymmetries of the ring length. Further, we compare how the effective potentials change when mutual ring threading is restricted and we characterise the threading depth distributions at different center-of-mass ring separations.
引用
收藏
页数:12
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