Reversible pH- and solvent-responsive micelle-mediated self-assembly of platinum(II) terpyridyl-based metallo-supramolecular diblock copolymers

被引：55
|
作者：
Yam, Vivian Wing-Wah [1 ]
Hu, Yongchen [1 ]
Chan, Kenneth Hoi-Yiu [1 ]
Chung, Clive Yik-Sham [1 ]
机构：
[1] Univ Hong Kong, Dept Chem, Ctr Carbon Rich Mol & Nanoscale Met Based Mat Res, Hong Kong, Hong Kong, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2009年 / 41期
关键词：
PROTON-TRANSFER REACTIONS; ALPHA-DIIMINE LIGANDS; CRYSTAL-STRUCTURE; RED FORM; ELECTRONIC SPECTROSCOPY; LUMINESCENCE PROPERTIES; STRUCTURAL-PROPERTIES; TRANSITION-METALS; ALKYNYL COMPLEXES; ROOM-TEMPERATURE;
D O I：
10.1039/b911657e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An amphiphilic platinum(II)-containing diblock copolymer, with pH-and solvent-responsive micellization properties that could induce drastic UV-vis and emission spectral changes via modulation of Pt center dot center dot center dot Pt and pi-pi stacking interactions, has been demonstrated in both aqueous and organic media.
引用
收藏
页码：6216 / 6218
页数：3
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