Selective determination of Ag plus using Salecan derived nitrogen doped carbon dots as a fluorescent probe

被引:30
|
作者
Li, Junjian [1 ]
Zuo, Gancheng [1 ]
Qi, Xiaoliang [1 ]
Wei, Wei [1 ]
Pan, Xiaohao [1 ]
Su, Ting [1 ]
Zhang, Jianfa [1 ]
Dong, Wei [1 ]
机构
[1] Nanjing Univ Sci & Technol, Sch Chem Engn, Nanjing 210094, Jiangsu, Peoples R China
基金
中国国家自然科学基金;
关键词
Salecan; Nitrogen doped carbon dots; Ag plus detection; Fluorescence quenching; QUANTUM DOTS; GREEN SYNTHESIS; PHYSIOLOGICAL PH; LIVING CELLS; HUMAN SERUM; NANODOTS; SEMICONDUCTOR; SENSOR; ACIDS; IONS;
D O I
10.1016/j.msec.2017.04.007
中图分类号
TB3 [工程材料学]; R318.08 [生物材料学];
学科分类号
0805 ; 080501 ; 080502 ;
摘要
We report that nitrogen doped carbon dots (N-CDs) represent a viable fluorescent probe for the determination of Ag+. The N-CDs can be fairly easily prepared by a hydrothermal treatment method using Salecan and dicyandiamide as the precursors, display excitation/emission maxima of 350/438 nm. The N-CDs have an average diameter of about 3.8 nm. The N-CDs exhibited blue fluorescence (quantum yield of 13.2%) and could response to Ag+ selectively and sensitively. Other ions nearly had no interference. The probe has excellent selectivity, high sensitivity, and a linear response range that extends from 0 to 40 W. The limit of detection is as low as 1.12 x 10(-7) mol/L. The method was applied to the determination of Ag+ dissolved in water. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码:508 / 512
页数:5
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