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Selective determination of Ag plus using Salecan derived nitrogen doped carbon dots as a fluorescent probe
被引:30
|作者:
Li, Junjian
[1
]
Zuo, Gancheng
[1
]
Qi, Xiaoliang
[1
]
Wei, Wei
[1
]
Pan, Xiaohao
[1
]
Su, Ting
[1
]
Zhang, Jianfa
[1
]
Dong, Wei
[1
]
机构:
[1] Nanjing Univ Sci & Technol, Sch Chem Engn, Nanjing 210094, Jiangsu, Peoples R China
来源:
MATERIALS SCIENCE & ENGINEERING C-MATERIALS FOR BIOLOGICAL APPLICATIONS
|
2017年
/
77卷
基金:
中国国家自然科学基金;
关键词:
Salecan;
Nitrogen doped carbon dots;
Ag plus detection;
Fluorescence quenching;
QUANTUM DOTS;
GREEN SYNTHESIS;
PHYSIOLOGICAL PH;
LIVING CELLS;
HUMAN SERUM;
NANODOTS;
SEMICONDUCTOR;
SENSOR;
ACIDS;
IONS;
D O I:
10.1016/j.msec.2017.04.007
中图分类号:
TB3 [工程材料学];
R318.08 [生物材料学];
学科分类号:
0805 ;
080501 ;
080502 ;
摘要:
We report that nitrogen doped carbon dots (N-CDs) represent a viable fluorescent probe for the determination of Ag+. The N-CDs can be fairly easily prepared by a hydrothermal treatment method using Salecan and dicyandiamide as the precursors, display excitation/emission maxima of 350/438 nm. The N-CDs have an average diameter of about 3.8 nm. The N-CDs exhibited blue fluorescence (quantum yield of 13.2%) and could response to Ag+ selectively and sensitively. Other ions nearly had no interference. The probe has excellent selectivity, high sensitivity, and a linear response range that extends from 0 to 40 W. The limit of detection is as low as 1.12 x 10(-7) mol/L. The method was applied to the determination of Ag+ dissolved in water. (C) 2017 Elsevier B.V. All rights reserved.
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页码:508 / 512
页数:5
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