Synthesis of Substituted Naphtho-Ferrocenes via a Gold(I)-Catalyzed Intramolecular 6-endo-Dig Cyclization

被引：12

作者：

Zhang, Pei-Chao ^{[1
]}

Wang, Yidong ^{[1
]}

Qian, Deyun ^{[1
]}

Li, Wenbo ^{[1
]}

Zhang, Junliang ^{[1
,2
]}

机构：

[1] East China Normal Univ, Shanghai Key Lab Green Chem & Chem Proc, Sch Chem & Mol Engn, Shanghai 200062, Peoples R China

[2] Chinese Acad Sci, State Key Lab Organomet Chem, Shanghai Inst Organ Chem, Shanghai 200032, Peoples R China

来源：

CHINESE JOURNAL OF CHEMISTRY | 2017年 / 35卷 / 06期

基金：

中国国家自然科学基金;

关键词：

gold(I)-catalysis; cyclization; hydroarylation; PAHs-metallocenes; naphtho-ferrocenes; PLANAR CHIRAL FERROCENES; ENANTIOSELECTIVE SYNTHESIS; CYCLOISOMERIZATION; PHENANTHRENES; HETEROARENES; FULLERENE; DIASTEREO; EFFICIENT; AMIDES;

D O I：

10.1002/cjoc.201600886

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel series of naphtho-ferrocene derivatives were synthesized in high yields by an efficient gold-catalyzed intramolecular 6-endo-dig cyclization strategy. The salient features of this reaction include easy operation, broad substrate scope, high yields, mild conditions and it works well in wet solvent under air at room temperature.

引用

页码：849 / 852

页数：4

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