Diaminophosphinoboranes: effective reagents for phosphinoboration of CO2

被引：23

作者：

Szynkiewicz, Natalia ^{[1
]}

Ordyszewska, Anna ^{[1
]}

Chojnacki, Jarostaw ^{[1
]}

Grubba, Rafal ^{[1
]}

机构：

[1] Gdansk Univ Technol, Fac Chem, Dept Inorgan Chem, G Narutowicza St 11-12, PL-80233 Gdansk, Poland

来源：

RSC ADVANCES | 2019年 / 9卷 / 48期

关键词：

FRUSTRATED LEWIS PAIRS; CARBON-DIOXIDE BINDING; BOND COVALENT RADII; ACTIVATION; HYDROGENATION; REDUCTION; METHANOL;

D O I：

10.1039/c9ra06638a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The monomeric diaminophosphinoboranes readily react with CO2 under mild conditions to cleanly form products of the general formula in the absence of a catalyst. The isolated products from the CO2-phosphinoboration were fully characterized by NMR spectroscopy, IR spectroscopy, and X-ray diffraction. The mechanism of CO2 phosphinoboration with diaminophosphinoboranes was elucidated by DFT calculations.

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收藏

页码：27749 / 27753

页数：5

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