New architectures in hydrogen bond catalysis

被引：34
|
作者：
Rodriguez, Andrew A. [1 ]
Yoo, Hoseong [1 ]
Ziller, Joseph W. [1 ]
Shea, Kenneth J. [1 ]
机构：
[1] Univ Calif Irvine, Dept Chem, Irvine, CA 92697 USA
来源：
TETRAHEDRON LETTERS | 2009年 / 50卷 / 49期
关键词：
BAYLIS-HILLMAN REACTION; ASYMMETRIC CATALYSIS; BIFUNCTIONAL ORGANOCATALYST; DONORS; ACCELERATION; RECOGNITION; DERIVATIVES; ACTIVATION; GUANIDINE; UREA;
D O I：
10.1016/j.tetlet.2009.09.129
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
New achiral sulfamide, phosphoric triamide, and thiophosphoric triamide compounds have been synthesized. Their activity as hydrogen bond catalysts for the Friedel-Crafts and Baylis-Hillman reactions compares favorably with that of a known and an active thiourea catalyst. The new compounds were also studied by X-ray crystallography and their solid state structures are described. (C) 2009 Elsevier Ltd. All rights reserved.
引用
收藏
页码：6830 / 6833
页数：4
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