Fabrication of Artificial Opals by Electric-Field-Assisted Vertical Deposition

被引：54

作者：

Napolskii, Kirill S. ^{[1
]}

Sapoletova, Nina A. ^{[1
]}

Gorozhankin, Dmitriy F. ^{[1
]}

Eliseev, Andrey A. ^{[1
]}

Chernyshov, Dmitry Yu. ^{[2
]}

Byelov, Dmytro V. ^{[3
]}

Grigoryeva, Natalia A. ^{[4
]}

Mistonov, Alexander A. ^{[4
]}

Bouwman, Wim G. ^{[5
]}

Kvashnina, Kristina O. ^{[6
]}

Lukashin, Alexey V. ^{[1
]}

Snigirev, Anatoly A. ^{[6
]}

Vassilieva, Alexandra V. ^{[7
]}

Grigoriev, Sergey V. ^{[7
]}

Petukhov, Andrei V. ^{[3
]}

机构：

[1] Moscow MV Lomonosov State Univ, Dept Mat Sci, Moscow 119991, Russia

[2] Swiss Norwegian Beamlines European Synchrotron Ra, F-38043 Grenoble, France

[3] Univ Utrecht, Debye Inst Nanomat Sci, Vant Hoff Lab Phys & Colloid Chem, NL-3584 CH Utrecht, Netherlands

[4] St Petersburg State Univ, Dept Phys, St Petersburg 198504, Russia

[5] Delft Univ Technol, Fac Appl Sci, NL-2629 JB Delft, Netherlands

[6] European Synchrotron Radiat Facil, F-38043 Grenoble, France

[7] Petersburg Nucl Phys Inst, St Petersburg 188300, Russia

来源：

LANGMUIR | 2010年 / 26卷 / 04期

关键词：

X-RAY-DIFFRACTION; PHOTONIC CRYSTALS; ELECTROPHORETIC DEPOSITION; COLLOIDAL CRYSTALS; MULTILAYERS; BANDGAP;

D O I：

10.1021/la902793b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We present a new technique for large-scale fabrication of colloidal crystals with controllable quality and thickness. The method is based oil vertical deposition in the presence of a DC electric field normal to the conducting substrate. The crystal structure and quality are quantitatively characterized by microradian X-ray diffraction, scanning electron microscopy, and optical reflectometry. Attraction between the charged colloidal spheres and the substrate promotes growth of thicker crystalline Films, while the best-quality crystals are formed in the presence of repulsion. Highly ordered thick crystalline layers with a small amount of stacking faults and a low mosaic spread can be obtained by optimizing the growth conditions.

引用

页码：2346 / 2351

页数：6

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