A copper- and amine-free Sonogashira-type coupling procedure catalyzed by oxime palladacycles

被引：169

作者：

Alonso, DA ^{[1
]}

Nájera, C ^{[1
]}

Pacheco, MC ^{[1
]}

机构：

[1] Univ Alicante, Fac Ciencias, Dept Quim Organ, Alicante 03080, Spain

来源：

TETRAHEDRON LETTERS | 2002年 / 43卷 / 51期

关键词：

alkynes; coupling reactions; palladium catalysis;

D O I：

10.1016/S0040-4039(02)02335-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Oxime palladacycle derived from 4,4'-dichlorobenzophenone was found to promote the Sonogashira reaction of aryl iodides and aryl bromides with terminal acetylenes using I equivalent of tetrabutylammonium acetate in organic solvents generally in 1 h at 110degreesC and in high TONs (up to 72000). (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：9365 / 9368

页数：4

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