Ligand manipulation and design for ruthenium metathesis and tandem metathesis-hydrogenation catalysis

被引：36

作者：

Fogg, DE ^{[1
]}

Amoroso, D ^{[1
]}

Drouin, SD ^{[1
]}

Snelgrove, J ^{[1
]}

Conrad, J ^{[1
]}

Zamanian, F ^{[1
]}

机构：

[1] Univ Ottawa, Dept Chem, Ctr Catalysis Innovat & Res, Ottawa, ON K1N 6N5, Canada

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2002年 / 190卷 / 1-2期

关键词：

ruthenium; metathesis; hydrogenation; selectivity; diphosphines;

D O I：

10.1016/S1381-1169(02)00242-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Results of investigations into tandem ring-opening metathesis polymerization (ROMP)-hydrogenation are reviewed, in which hydrogen and 3-chloro-3-methyl-1-butyne provide simple chemical toggles to switch between metathesis and hydrogenation chemistry, enabling multiple tandem catalysis in chlorocarbon solvent. In the presence of methanol, hydrogenation of metathesis polymers can be carried out under 1 atm H-2. Issues of ligand design are examined in developing new Ru-diphosphine catalysts with improved selectivity, and an important decomposition pathway is identified for RuCl2 (PP)(CHR) systems (PP = chelating diphosphine). (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：177 / 184

页数：8

共 44 条

[1] Ring-opening metathesis polymerization via ruthenium complexes of chelating diphosphines [J].

Amoroso, D ;

Fogg, DE .

MACROMOLECULES, 2000, 33 (08) :2815-2818

[2] A stable silylene in a reactive environment:: Synthesis, reactivity, and silicon extrusion chemistry of a coordinatively unsaturated ruthenium silylene complex containing chloride and η3-P-C-P ligands [J].

Amoroso, D ;

Haaf, M ;

Yap, GPA ;

West, R ;

Fogg, DE .

ORGANOMETALLICS, 2002, 21 (03) :534-540

[3]

Amoroso D, 2001, CAN J CHEM, V79, P958

[4]

AMOROSO D, UNPUB ORGANOMETALLIC

[5]

AMOROSO D, 2002, IN PRESS ORGANOMETAL

[6] ELECTRONIC STABILIZATION OF NUCLEOPHILIC CARBENES [J].

ARDUENGO, AJ ;

DIAS, HVR ;

HARLOW, RL ;

KLINE, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (14) :5530-5534

[7] Tandem catalysis: Three mechanistically distinct reactions from a single ruthenium complex [J].

Bielawski, CW ;

Louie, J ;

Grubbs, RH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (51) :12872-12873

[8] THE INDUSTRIAL SYNTHESIS OF BIMODAL POLYETHYLENE GRADES WITH IMPROVED PROPERTIES [J].

BOHM, LL ;

ENDERLE, HF ;

FLEISSNER, M .

CATALYST DESIGN FOR TAILOR-MADE POLYOLEFINS, 1994, 89 :351-363

[9] Homogeneous metathesis polymerization by well-defined group VI and group VIII transition-metal alkylidenes: Fundamentals and applications in the preparation of advanced materials [J].

Buchmeiser, MR .

CHEMICAL REVIEWS, 2000, 100 (04) :1565-1604

[10] Modular phospholane ligands in asymmetric catalysis [J].

Burk, MJ .

ACCOUNTS OF CHEMICAL RESEARCH, 2000, 33 (06) :363-372

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