Hydroisomerization of hexacyclo[9.2.1.02,10.03,8.04,6.05,9] tetradecanes to diamantane induced by ionic liquids

被引：9

作者：

Aminov, Rishat, I ^{[1
]}

Akshieva, Aida N. ^{[1
]}

Khusnutdinov, Ravil, I ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Petrochem & Catalysis, Pr Oktyabrya 141, Ufa 450075, Russia

来源：

CATALYSIS COMMUNICATIONS | 2019年 / 130卷

关键词：

Diamantane; Ionic liquid; Hydroisomerization [4+2]-dimers of norbornadiene; DIAMONDOID CAGE HYDROCARBONS; POLYCYCLIC-HYDROCARBONS; ISOMERIZATION; REARRANGEMENT; DIMERIZATION;

D O I：

10.1016/j.catcom.2019.105756

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Hydroisomerization of endo-endo-, exo-exo-, exo-endo-, and endo-exo-, hexacyclo[9.2.1.0(2,10).0(3,8).0(4,6).0(5,9)]tetra-decanes to diamantane was performed for the first time in 80-96% yields under the action of ionic liquids (ILs), [Et3NH](+)[Al2Cl7](-) and [BMIM](+)[Fe2Cl7](-). Ionic liquids have multiple functions, promoting the following reactions of hexacyclotetradecanes: hydrogenation, dehydrogenation, and skeletal rearrangement; simultaneously, they serve as HCl donors.

引用

页数：5

共 35 条

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