Corrosion and tribological behaviors of chromium oxide coatings prepared by the glow-discharge plasma technique

In order to improve the corrosion and tribological properties of steel, chromium oxide coatings were prepared by a new combined process, namely, chromizing and plasma oxidizing treatments using double glow plasma technology under various oxygen flow rates. The composition and microstructure of the coatings were analyzed respectively by means of X-ray diffraction, scanning electron microscopy and transmission electron microscopy. The results indicated that the oxygen flow rates had a great effect on the surface structure of the prepared Cr2O3 coatings, and dense and smooth Cr2O3 coatings were prepared at the oxygen flow rate of 10 sccm. The Cr2O3 coatings exhibited the better corrosion resistance which was in good agreement with the results obtained by the microstructure studied. Further mechanical properties test showed that the Cr2O3 coatings with high hardness and elastic modulus adhered well to the steel substrates and displayed excellent wear resistance and low coefficient of friction under dry sliding wear test conditions. The wear mechanism was mostly dominated by the "soft abrasion". (C) 2009 Elsevier B.V. All rights reserved.