Polar domains on globular macromolecules: Shape-persistent, amphiphilic tridendrons

被引：23

作者：

Pesak, DJ

Moore, JS

机构：

[1] UNIV ILLINOIS,BECKMAN INST ADV SCI & TECHNOL,DEPT CHEM,URBANA,IL 61801

[2] UNIV ILLINOIS,BECKMAN INST ADV SCI & TECHNOL,DEPT MAT SCI & ENGN,URBANA,IL 61801

来源：

TETRAHEDRON | 1997年 / 53卷 / 45期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0040-4020(97)00966-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A series of asymmetric phenylacetylene tridendrons is prepared by coupling polar monodendrons having t-butyl esters on their periphery with a non-polar monodendron having t-butyl groups on its periphery. Subsequent conversion of the t-butyl esters to carboxylic acids by thermolysis gives amphiphilic dendrimers having polar domains of various size. The characterization and solution phase behavior of these structures is discussed. (C) 1997 Elsevier Science Ltd.

引用

收藏

页码：15331 / 15347

页数：17

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