Synthesis and characterization of a novel 3D copper(I) coordination polymer with a ligand generated in situ

被引：22

作者：

Huang, Xi-He ^{[1
]}

Sheng, Tian-Lu ^{[1
]}

Xiang, Sheng-Chang ^{[1
]}

Fu, Rui-Biao ^{[1
]}

Hu, Sheng-Min ^{[1
]}

Li, Ya-Min ^{[1
]}

Wu, Xin-Tao ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2006年 / 9卷 / 12期

基金：

中国国家自然科学基金;

关键词：

copper; tetrazolate; in situ; hydrothermal synthesis; coordination polymer;

D O I：

10.1016/j.inoche.2006.08.011

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Hydrothermal reaction of CuCl2 center dot 2H(2)O, NaN3 With 1,4-dicyanobenzene in water/ethanol yielded a novel Cu(l)-tetrazolate, {Cu(cptz)}(n), (1) (Heptz is 5-(4-cyanophenyl)-tetrazole). The cptz ligand in the complex was generated in situ through the [2 + 3] cycloaddition reaction involving one of the two cyano-groups of the precursor 1,4-dicyanobenzene. The structure characterization shows that 1 possesses a 3D 4-connected SrAl2 topological network. Additionally, complex 1 exhibits strong yellow fluorescence at room temperature in the solid state. (C) 2006 Elsevier B.V. All rights reserved.

引用

页码：1304 / 1307

页数：4

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