Aggregation-induced blue shift of fluorescence emission due to suppression of TICT in a phenothiazine-based organogel

被引：74

作者：

Yang, Xinchun ^{[1
]}

Lu, Ran ^{[1
]}

Zhou, Huipeng ^{[1
]}

Xue, Pengchong ^{[1
]}

Wang, Fengyong ^{[1
]}

Chen, Peng ^{[1
]}

Zhao, Yingying ^{[1
]}

机构：

[1] Jilin Univ, Coll Chem, State Key Lab Supramol Struct & Mat, Changchun 130012, Peoples R China

来源：

JOURNAL OF COLLOID AND INTERFACE SCIENCE | 2009年 / 339卷 / 02期

基金：

中国国家自然科学基金;

关键词：

Supramolecular organogel; Self-assembly; Fluorescence; TICT; ELECTRON-TRANSFER; EXCITED-STATE; DERIVATIVES; CHOLESTEROL; PORPHYRINS; ULTRASOUND; GELATOR; ENERGY;

D O I：

10.1016/j.jcis.2009.07.033

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A new D-pi-A type gelator based on a phenothiazine derivative, which can gel cyclohexane, hexane, and ethanol/water under ultrasound treatment, has been synthesized. Because such gelators can act as twisted intermolecular charge transfer (TICT) probes, their emission in solution can be tuned by varying the polarity of the solvents. It is notable that an unusual aggregation-induced blue shift of the emission has been detected on account of the suppression of TICT in the gel phase. (C) 2009 Elsevier Inc. All rights reserved.

引用

页码：527 / 532

页数：6

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