Tunable Aryl Alkyl Ionic Liquids (TAAILs): The Next Generation of Ionic Liquids

被引：152

作者：

Ahrens, Sebastian ^{[2
]}

Peritz, Anke ^{[1
]}

Strassner, Thomas ^{[1
]}

机构：

[1] Tech Univ Dresden, D-01062 Dresden, Germany

[2] BASF SE, D-67056 Ludwigshafen, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 42期

关键词：

imidazolium salts; ionic liquids; substituent effects; TAAILs;

D O I：

10.1002/anie.200903399

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The combination of aromatic and aliphatic substituents at the imidazolium ring leads to a new generation of imidazolium-based ionic liquids (TAAILs: tunable aryl alkyl ionic liquids; see charge distribution of the methoxyphenyl methyl derivative). Electronic interaction between the aromatic substituent and the imidazolium core allows the properties ofthese species to be tuned more precisely than is possible for currently available ionic liquids. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：7908 / 7910

页数：3

共 11 条

[1]

Davis J.H., 2008, IONIC LIQUIDS SYNTHE, P45

[2]

Eicher Theophil, 2013, The Chemistry of Heterocycles: Structures, Reactions, Synthesis, and Applications

[3] Homogeneous catalysis in ionic liquids [J].

Giernoth, Ralf .

IN SITU NMR METHODS IN CATALYSIS, 2007, 276 :1-23

[4] Synthesis and mesomorphic properties of rigid-core ionic liquid crystals [J].

Kouwer, Paul H. J. ;

Swager, Timothy M. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (45) :14042-14052

[5]

MEYER DJ, UNPUB

[6] Applications of ionic liquids in the chemical industry [J].

Plechkova, Natalia V. ;

Seddon, Kenneth R. .

CHEMICAL SOCIETY REVIEWS, 2008, 37 (01) :123-150

[7]

Strassner T., 2009, Patent No. [WO 2009095012A1, 2009095012]

[8]

STRASSNER T, UNPUB

[9]

Strassner T, 2007, TOP ORGANOMETAL CHEM, V22, P125, DOI 10.1007/3418_040

[10] New Pd-NHC-complexes for the Mizoroki-Heck reaction [J].

Taige, Maria A. ;

Zeller, Alexander ;

Ahrens, Sebastian ;

Goutal, Sigrid ;

Herdtweck, Eberhardt ;

Strassner, Thomas .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2007, 692 (07) :1519-1529

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