Pd(II)-Catalyzed Hydroxylation of Arenes with 1 atm of O2 or Air

被引：383

作者：

Zhang, Yang-Hui ^{[1
]}

Yu, Jin-Quan ^{[1
]}

机构：

[1] Scripps Res Inst, Dept Chem, La Jolla, CA 92037 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 41期

基金：

美国国家科学基金会;

关键词：

C-H BONDS; OXYGEN INSERTION; OXIDATION; BENZOQUINONE; ACTIVATION; PEROXIDES; COMPLEXES; MECHANISM; DIOXYGEN; METHANOL;

D O I：

10.1021/ja907198n

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Pd(II)-catalyzed ortho-hydroxylation of variously substituted benzoic acids under 1 atm of O-2 or air is achieved under nonacidic conditions. Extensive labeling studies support a direct oxygenation of aryl C-H bonds with molecular oxygen.

引用

页码：14654 / +

页数：3

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