Synthesis and crystal structure of Na2[RuNOCl5]•6H2O

被引：7

作者：

Emel'yanov, VA ^{[1
]}

Gromilov, SA ^{[1
]}

Baidina, IA ^{[1
]}

Virovets, AV ^{[1
]}

Belyaev, AV ^{[1
]}

Logvinenko, VA ^{[1
]}

机构：

[1] Russian Acad Sci, Siberian Branch, Inst Inorgan Chem, Novosibirsk, Russia

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 1999年 / 40卷 / 06期

关键词：

Sodium Salt; Chlorine Atom; Coordination Polyhedron; Complex Anion; Nitroso;

D O I：

10.1007/BF02700696

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A procedure for the synthesis of Na-2[RuNOCl5]. 6H(2)O is described. The complete was studied by IR spectroscopy and by thermal, X-ray phase, and X-l-ay diffraction analyses. Crystal data: a = 26.740(7), b = 31.581(7), c = 6.918(3) Angstrom, V = 5842(3) Angstrom(3), space group Fdd2, Z = 16, d(calc) = 2.103, d(exp) = 2.112 g/cm(3). The structure consists of [RUNOCl5](2-) complex cations, Na+ cations, and crystallization water molecules. The compound is stable in conditions of high humidity of atmosphere but irreversibly loses up to four water molecules when stored in dry atmosphere. Removal of two water molecules is accompanied by crystal decay and changes in the crystal structure. Hearing the substance above 100 degrees C leads to a hygroscopic anhydrous complex Na-2[RuNOCl5], which is stable below t = 375 degrees C.

引用

页码：883 / 891

页数：9

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