Carbene Complexes Made Easily: Decomposition of Reissert Compounds and Further Synthetic Approaches

被引：28

作者：

Bittermann, Agnes ^{[1
]}

Baskakov, Denys ^{[1
]}

Herrmann, Wolfgang A. ^{[1
]}

机构：

[1] Tech Univ Munich, Dept Chem, Chair Inorgan Chem, D-85747 Garching, Germany

来源：

ORGANOMETALLICS | 2009年 / 28卷 / 17期

关键词：

N-HETEROCYCLIC CARBENES; TRANSITION-METAL-COMPLEXES; GROUP-TRANSFER POLYMERIZATION; CROSS-COUPLING REACTIONS; IRIDIUM COMPLEXES; PALLADIUM; LIGANDS; NHC; PRECURSORS; REACTIVITY;

D O I：

10.1021/om900354v

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New methods for the preparation of NHC-metal complexes have been developed. It was shown that a nitrile group in Reissert analogous compounds can act as a good leaving group in thermal elimination, resulting in carbene formation. Moreover potassium carbonate was introduced as a highly efficient and mild reagent for the generation of N-heterocyclic carbene complexes in good to excellent yields, even in water, as the most environmentally friendly medium.

引用

页码：5107 / 5111

页数：5

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