Selectivity in the Elaboration of Bicyclic Borazarenes

被引：29

作者：

Bhattacharjee, Ayan ^{[1
]}

Davies, Geraint H. M. ^{[2
]}

Saeednia, Borna ^{[1
]}

Wisniewski, Steven R. ^{[3
]}

Molander, Gary A. ^{[1
]}

机构：

[1] Univ Penn, Dept Chem, 231 South 34th St, Philadelphia, PA 19104 USA

[2] Bristol Myers Squibb Co, Small Mol Drug Dev, 200 Cambridge Pk Dr, Cambridge, MA 02140 USA

[3] Bristol Myers Squibb Co, Chem Proc Dev, One Squibb Dr, New Brunswick, NJ 08903 USA

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2021年 / 363卷 / 09期

关键词：

Borazarenes; Bicyclics; Isosteres; Computations; Selectivity; ELECTROPHILIC AROMATIC-SUBSTITUTION; LATE-STAGE FUNCTIONALIZATION; C-H BORYLATION; OPTOELECTRONIC PROPERTIES; BROMINATED 2,1-BORAZARONAPHTHALENES; HETEROAROMATIC-COMPOUNDS; EFFICIENT SYNTHESIS; AZABORINE COMPOUNDS; CROSS-COUPLINGS; AB-INITIO;

D O I：

10.1002/adsc.202001384

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Among aromatic compounds, borazarenes represent a significant class of isosteres in which carbon-carbon bonds have been replaced by B-N bonds. Described herein is a summary of the selective reactions that have been developed for known systems, as well as a summary of computationally-based predictions of selectivities that might be anticipated in reactions of yet unrealized substructures.

引用

页码：2256 / 2273

页数：18

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