Stannous Chloride Dihydrate: A Novel and Efficient Catalyst for the Synthesis of gem-Dihydroperoxides from Ketones and Aldehydes

被引：30

作者：

Azarifar, Davood ^{[1
]}

Khosravi, Kaveh ^{[1
]}

Soleimanei, Fatemeh ^{[1
]}

机构：

[1] Bu Ali Sina Univ, Fac Chem, Hamadan 65178, Iran

来源：

SYNTHESIS-STUTTGART | 2009年 / 15期

关键词：

ketones; aldehydes; gem-dihydroperoxides; aqueous hydrogen peroxide; stannous chloride; AQUEOUS HYDROGEN-PEROXIDE; ANTIMALARIAL ACTIVITY; GEMINAL BISHYDROPEROXIDES; 1,2,4-TRIOXANES; HYDROPEROXIDE; 1,2,4,5-TETRAOXACYCLOALKANES; DISPIRO-1,2,4,5-TETRAOXANES; DERIVATIVES; ACETALS; IODINE;

D O I：

10.1055/s-0029-1217394

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Ketones and aldehydes undergo facile hydroperoxidation on treatment with aqueous hydrogen peroxide (30%) in the presence of 10 mol% stannous chloride dihydrate in acetonitrile tinder very mild conditions to afford the corresponding gem-dihydroperoxides in satisfactory yields.

引用

页码：2553 / 2556

页数：4

共 39 条

[1]

Adam W., 2000, Peroxide Chemistry Mechanistic and Preparative Aspects of Oxygen Transfer

[2]

Ando W., 1992, Organic peroxides

[3] Antimalarial chemotherapeutic peroxides: artemisinin, yingzhaosu A and related compounds [J].