Synthesis and crystal structure of (o-Diaminobenzene)2 Zn(OAc)2

被引：3

作者：

Mei, L. ^{[1
]}

Li, J. ^{[1
]}

Ming, Z. S. ^{[2
]}

Rong, L. Q. ^{[2
]}

Liang, L. X. ^{[1
]}

机构：

[1] Hefei Univ Technol, Hefei 230009, Peoples R China

[2] Univ Sci & Technol China, Hefei 230009, Peoples R China

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2009年 / 35卷 / 12期

关键词：

SCHIFF-BASE; COMPLEXES; NICKEL(II); COPPER(II); LIGANDS;

D O I：

10.1134/S107032840912001X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The treatment of o-diaminobenzene with Zn ( OAc )(2) center dot 2H(2)O in alcohol results in the formation of mononuclear bis(o-diaminobenzene)diacetate Zinc, Zn[C8H11N2O2](2). Its structure was determined by X-ray diffraction analysis. The complex is also characterized by elemental analysis, H-1 NMR and IR. The crystal is monoclinic space group C2, parameters: a = 16.297(5), b = 4.775(3), c = 11.664(5) , beta = 97.646(5)A degrees, lambda = 1.54184 , V = 899.6(7) (3), Z = 2, rho (c) = 1.476 g/cm(3), M (r) = 399.75, F(000) = 416.0, R (1) = 0.0594, wR (2) = 0.1439 for 995 observed reflections with I > 2 sigma(I).

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页码：871 / 873

页数：3

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