Adducts of nickel(II) acetylacetonate chelating with heterocyclic bases: 3-cyanopyridine and 4-cyanopyridine

被引：6

作者：

Zukerman-Schpector, J ^{[1
]}

Trindade, AC

Dunstan, PO

机构：

[1] Univ Sao Paulo, Inst Quim, Sao Paulo, Brazil

[2] Univ Fed Sao Carlos, Dept Quim, BR-13565905 Sao Carlos, SP, Brazil

[3] Univ Estadual Campinas, Inst Quim, Campinas, SP, Brazil

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2000年 / 56卷 / 07期

关键词：

D O I：

10.1107/S0108270100004662

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In both title compounds, (acetylacetonato-O,O')bis(3-cyanopyridine-N)nickel(II), (I), and (acetylacetonato-O,O')bis(4-cyanopyridine-N)nickel(II), (II), both [Ni(C5H7O2)(2)- (C6H4N2)(2)],the Ni-II atom, which is situated on a centre of symmetry, is octahedrally coordinated. Distances and angles for (I) and (II), respectively, are: Ni-O 2.009 (2)/2.016 (2) and 2.0110 (16)/2.0238 (18) Angstrom, Ni-N 2.116 (3) and 2.179 (2) Angstrom, O-Ni-O 91.86 (10) and 90.19 (7)degrees, and O- Ni-N 91.27 (11)/90.19 (11) and 89.65 (8)/90.79 (7)degrees.

引用

页码：763 / 765

页数：3

共 8 条

[1]

Cotton FA, 1997, CHEM COMMUN, P1673

[2] Thermochemistry of adducts of nickel(II) acetylacetonate chelate with heterocyclic bases [J].