Spectroscopic and Thermal Study of Mixed Ligand Complexes of Cobalt (II) with β-Diketones and Pyrazinamide.

被引：1

作者：

Zheleznova, L. ^{[1
]}

Sliusarchuk, L. ^{[1
]}

Rogovtsov, O. ^{[1
]}

Trunova, E. ^{[1
]}

机构：

[1] VI Vernadsky Inst Gen & Inorgan Chem NASU, 32-34 Palladina Prosp, UA-03142 Kiev, Ukraine

来源：

MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 2018年 / 672卷 / 01期

关键词：

Cobalt beta-diketonates complexes; synthesis; diffuse reflection spectra; IR-spectra; thermal analysis; RAY CRYSTAL-STRUCTURE; X-RAY; VIBRATIONAL-SPECTRA; IR-SPECTRA; RAMAN; MANGANESE(II); NICKEL(II); ANILINE; POLYMER; HALIDE;

D O I：

10.1080/15421406.2018.1542114

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis of mixed ligand of cobalt (II) with beta-diketones (beta-dik) (acetylacetone and hexafluoroacetylacetone) and pyrazinamide is proposed. The compounds were investigated by IR- and diffuse reflectance spectroscopies, differential thermal analysis. It is shown that Co (II) beta-diketonates (acetylacetone, hexafluoroacetylacetone) mixed ligand complexes with pyrazinamide have a structure corresponding to a distorted octahedron, having D-4h symmetry. The complexes are bonded through hydrogen bonds via water molecules.

引用

页码：123 / 132

页数：10

共 27 条

[11] AN INFRARED AND RAMAN-SPECTROSCOPIC STUDY OF PYRAZINECADMIUM(II) TETRACYANOMETALATE(II) BENZENE (1/1) CLATHRATES - CD(C4H4N2)CD(CN)4.C6H6 AND CD(C4H4N2)HG(CN)4.C6H6
EKICI, N
KANTARCI, Z
AKYUZ, S
[J]. JOURNAL OF INCLUSION PHENOMENA AND MOLECULAR RECOGNITION IN CHEMISTRY, 1991, 10 (01): : 9 - 18
[12] Gamov G. A., 2015, ROS KHIM ZH, P66
[13] Three coordinate copper(I) complexes.: Synthesis, spectral, and structural study of copper(I) complexes of 4-benzoylpyridine and X-ray crystal structure of the dimer [CuCl(4-benzoylpyridine)]2
Goher, MAS
Mak, TCW
[J]. POLYHEDRON, 1998, 17 (20) : 3485 - 3494
[14] Spectral and structural characterization of copper(I) halide, nitrate and perchlorate complexes of pyrazine carboxamide (pyza) and X-ray crystal structure of polymeric [Cu(pyza)2I]n complex
Goher, MAS
Mautner, FA
[J]. POLYHEDRON, 2000, 19 (06) : 601 - 606
[15] JAIN SC, 1976, J INDIAN CHEM SOC, V53, P537
[16] POLARIZED RAMAN AND INFRARED-SPECTRA OF PYRAZINAMIDE
KALKAR, AK
BHOSEKAR, NM
KSHIRSAGAR, ST
[J]. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1989, 45 (06): : 635 - 641
[17] Lever A.B.P., 1987, Inorganic electronic spectroscopy
[18] SINGLE-CRYSTAL ELECTRONIC-SPECTRA, ELECTRON-SPIN RESONANCE AND MAGNETIC DATA FOR SOME HIGH-SPIN TETRAGONAL COBALT(II) COMPLEXES AT CRYOGENIC TEMPERATURES
LEVER, ABP
WALKER, IM
MCCARTHY, PJ
[J]. INORGANICA CHIMICA ACTA-ARTICLES, 1980, 39 (01): : 81 - 90
[19] Nakamoto K., 2008, INFRARED RAMAN SPE A
[20] SANYAL GS, 1982, INDIAN J CHEM A, V21, P1044

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