Aqueous metal-organic solutions for YSZ thin film inkjet deposition

被引：33

作者：

Gadea, C. ^{[1
]}

Hanniet, Q. ^{[1
]}

Lesch, A. ^{[2
]}

Marani, D. ^{[1
]}

Jensen, S. H. ^{[1
]}

Esposito, V. ^{[1
]}

机构：

[1] Tech Univ Denmark, DTU Energy, Riso Campus,Frederiksborgvej 399, DK-4000 Roskilde, Denmark

[2] EPFL Valais Wallis, Lab Electrochim Phys & Analyt, Rue Ind 17, CH-1950 Sion, Switzerland

来源：

JOURNAL OF MATERIALS CHEMISTRY C | 2017年 / 5卷 / 24期

基金：

瑞士国家科学基金会;

关键词：

YTTRIA-STABILIZED-ZIRCONIA; OXIDE FUEL-CELL; ELECTROLYTE LAYERS; FABRICATION; CONDUCTIVITY;

D O I：

10.1039/c7tc01879g

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Inkjet printing of 8% Y2O3-stabilized ZrO2 (YSZ) thin films is achieved by designing a novel water-based reactive ink for Drop-on-Demand (DoD) inkjet printing. The ink formulation is based on a novel chemical strategy that consists of a combination of metal oxide precursors (zirconium alkoxide and yttrium salt), water and a nucleophilic agent, i.e. n-methyldiethanolamine (MDEA). This chemistry leads to metal-organic complexes with long term ink stability and high precision printability. Ink rheology and chemical reactivity are analyzed and controlled in terms of metal-organic interactions in the solutions. Thin dense nanocrystalline YSZ films below 150 nm are obtained by low temperature calcination treatments (400-500 C-circle), making the deposition suitable for a large variety of substrates, including silicon, glass and metals. Thin films and printed patterns achieve full densification with no lateral shrinkage and high ionic conductivity.

引用

页码：6021 / 6029

页数：9

共 52 条

[1]

[Anonymous], 2013, Surface Science Techniques, DOI DOI 10.1007/978-3-642-34243-1_1

[2] PORE NARROWING AND FORMATION OF ULTRATHIN YTTRIA-STABILIZED ZIRCONIA LAYERS IN CERAMIC MEMBRANES BY CHEMICAL-VAPOR-DEPOSITION ELECTROCHEMICAL VAPOR-DEPOSITION [J].

CAO, GZ ;

BRINKMAN, HW ;

MEIJERINK, J ;

DEVRIES, KJ ;

BURGGRAAF, AJ .

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1993, 76 (09) :2201-2208

[3]

Carter C.B., 2013, Ceramic Materials

[4] Fabrication, characterization and photocatalytic activity of TiO2 layers prepared by inkjet printing of stabilized nanocrystalline suspensions [J].

Cerna, Marcela ;

Vesely, Michal ;

Dzik, Petr ;

Guillard, Chantal ;

Puzenat, Eric ;

Lepicova, Martina .

APPLIED CATALYSIS B-ENVIRONMENTAL, 2013, 138 :84-94

[5] Study on chemical-solution-deposited lanthanum zirconium oxide film based on the Taguchi method [J].

Chen, Hsueh Shih ;

Kumar, Ramachandran Vasant ;

Glowacki, Bartlomiej Andrzej .

JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 2009, 51 (01) :102-111

[6] Inkjet printing of inorganic sol-gel ink and control of the geometrical characteristics [J].

Chouiki, Mustapha ;

Schoeftner, Rainer .

JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 2011, 58 (01) :91-95

[7] Inkjet catalyst printing and electroless copper deposition for low-cost patterned microwave passive devices on paper [J].

Cook, Benjamin S. ;

Fang, Yunnan ;

Kim, Sangkil ;

Le, Taoran ;

Goodwin, W. Brandon ;

Sandhage, Kenneth H. ;

Tentzeris, Manos M. .

ELECTRONIC MATERIALS LETTERS, 2013, 9 (05) :669-676

[8] Inkjet Printing of Functional and Structural Materials: Fluid Property Requirements, Feature Stability, and Resolution [J].

Derby, Brian .

ANNUAL REVIEW OF MATERIALS RESEARCH, VOL 40, 2010, 40 :395-414

[9] Thin-film solid oxide fuel cell with high performance at low-temperature [J].

deSouza, S ;

Visco, SJ ;

DeJonghe, LC .

SOLID STATE IONICS, 1997, 98 (1-2) :57-61

[10] An anode-supported solid oxide fuel cell with spray-coated yttria-stabilized zirconia (YSZ) electrolyte film [J].

Ding, Jiao ;

Liu, Jiang .

SOLID STATE IONICS, 2008, 179 (21-26) :1246-1249

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