Nonhomogeneous textures and banded flow in a soft cubic phase under shear

被引:84
作者
Eiser, E [1 ]
Molino, F
Porte, G
Diat, O
机构
[1] Univ Montpellier 2, Dynam Phases Condensees Grp, F-34095 Montpellier 05, France
[2] European Synchrotron Radiat Facil, F-38043 Grenoble, France
来源
PHYSICAL REVIEW E | 2000年 / 61卷 / 06期
关键词
D O I
10.1103/PhysRevE.61.6759
中图分类号
O35 [流体力学]; O53 [等离子体物理学];
学科分类号
070204 ; 080103 ; 080704 ;
摘要
We report evidence for two distinct strain-induced orientation transitions in a lyotropic bce cubic crystal submitted to increasing shear rates. The crystal is built up from copolymer spherical micelles in a selective solvent. The distribution of orientations is characterized by x-ray diffraction: in the two oriented states, the dense [111] rows align along the flow, but they differ from each other in the orientations of the dense layers with respect to the sheer plane. These orientation transitions have clear rheological signatures in the form of two stress plateaus each associated with the coexistence of two states of orientation We compare this behavior with the well documented shear-induced orientation transition in wormlike micelles.
引用
收藏
页码:6759 / 6764
页数:6
相关论文
共 23 条
[1]   SHEAR-INDUCED MELTING [J].
ACKERSON, BJ ;
CLARK, NA .
PHYSICAL REVIEW LETTERS, 1981, 46 (02) :123-126
[2]   SHEAR-INDUCED PARTIAL TRANSLATIONAL ORDERING OF A COLLOIDAL SOLID [J].
ACKERSON, BJ ;
CLARK, NA .
PHYSICAL REVIEW A, 1984, 30 (02) :906-918
[3]   MICELLIZATION OF POLY(ETHYLENE OXIDE)-POLY(PROPYLENE OXIDE)-POLY(ETHYLENE OXIDE) TRIBLOCK COPOLYMERS IN AQUEOUS-SOLUTIONS - THERMODYNAMICS OF COPOLYMER ASSOCIATION [J].
ALEXANDRIDIS, P ;
HOLZWARTH, JF ;
HATTON, TA .
MACROMOLECULES, 1994, 27 (09) :2414-2425
[4]   ISOTROPIC-TO-NEMATIC TRANSITION IN WORMLIKE MICELLES UNDER SHEAR [J].
BERRET, JF ;
ROUX, DC ;
PORTE, G .
JOURNAL DE PHYSIQUE II, 1994, 4 (08) :1261-1279
[5]   Bistability in non-Newtonian flow: Rheology of lyotropic liquid crystals [J].
Bonn, D ;
Meunier, J ;
Greffier, O ;
Al-Kahwaji, A ;
Kellay, H .
PHYSICAL REVIEW E, 1998, 58 (02) :2115-2118
[6]   THE RHEOLOGY OF ENTANGLED POLYMERS AT VERY HIGH SHEAR RATES [J].
CATES, ME ;
MCLEISH, TCB ;
MARRUCCI, G .
EUROPHYSICS LETTERS, 1993, 21 (04) :451-456
[7]   RHEOLOGICAL AND MICROSTRUCTURAL TRANSITIONS IN COLLOIDAL CRYSTALS [J].
CHEN, LB ;
CHOW, MK ;
ACKERSON, BJ ;
ZUKOSKI, CF .
LANGMUIR, 1994, 10 (08) :2817-2829
[8]   GAP SIZE AND SHEAR HISTORY DEPENDENCIES IN SHEAR THICKENING OF A SUSPENSION ORDERED AT REST [J].
CHOW, MK ;
ZUKOSKI, CF .
JOURNAL OF RHEOLOGY, 1995, 39 (01) :15-32
[9]   OBSERVATION OF THE COUPLING OF CONCENTRATION FLUCTUATIONS TO STEADY-STATE SHEAR-FLOW [J].
CLARK, NA ;
ACKERSON, BJ .
PHYSICAL REVIEW LETTERS, 1980, 44 (15) :1005-1008
[10]   Shear-induced orientation of the body-centered-cubic phase in a diblock copolymer gel [J].
Hamley, IW ;
Pople, JA ;
Booth, C ;
Derici, L ;
Impéror-Clerc, M ;
Davidson, P .
PHYSICAL REVIEW E, 1998, 58 (06) :7620-7628