A new catalytic route for the activation of sp-hybridized carbon-hydrogen bonds

被引：36
作者：
Marciniec, Bogdan [1 ]
Dudziec, Beata [1 ]
Kownacki, Ireneusz [1 ]
机构：
[1] Adam Mickiewicz Univ, Fac Chem, Dept Organomet Chem, PL-60780 Poznan, Poland
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 48期
关键词：
alkynes; C-H activation; homogeneous catalysis; ruthenium; silanes;
D O I：
10.1002/anie.200603582
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Chemical Equation Presented) Vinyl-substituted silicon compounds react selectively with terminal alkynes in the presence of complexes containing [Ru]-H and [Ru]-Si bonds to form functionalized silylethynes (see picture). This reaction opens up a new catalytic route for the preparation of a class of potent organosilicon reagents for organic synthesis. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
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收藏
页码：8180 / 8184
页数：5
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