High Temperature Co-Electrolysis for Power-to-X

被引:21
作者
Duenas, Diana Maria Amaya [1 ]
Riedel, Marc [1 ]
Riegraf, Matthias [1 ]
Costa, Remi [1 ]
Friedrich, Kaspar Andreas [1 ,2 ]
机构
[1] German Aerosp Ctr, Inst Engn Thermodynam, Electrochem Energy Technol, Pfaffenwaldring 38-40, D-70569 Stuttgart, Germany
[2] Univ Stuttgart, Inst Bldg Energet Thermal Engn & Energy Storage I, Pfaffenwaldring 31, D-70569 Stuttgart, Germany
关键词
Co-electrolysis; CO2; reduction; Pressurized operation; Solid oxide cell; Syngas; ANODES; SULFUR; CELLS; SOFC; DEGRADATION; H2O;
D O I
10.1002/cite.201900119
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
High temperature solid oxide cells are attractive electrochemical reactors to perform simultaneous reduction of steam and CO2 into syngas with the possibility of delivering a tailored composition to downstream processes. The main thermodynamic considerations, performance and impedance curves of electrolyte supported cells in co-electrolysis are shown as a function of temperature and pressure. In dynamic operation, the thermal changes that the reactor undergoes appear stronger in co-electrolysis mode than in steam electrolysis and should be considered in the development of operating strategies.
引用
收藏
页码:45 / 52
页数:8
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