Excess molar volumes and viscosities for binary mixtures of propylene glycol monomethyl ether with methacrylic acid, benzyl methacrylate, and 2-hydroxyethyl methacrylate at (298.15, 308.15, and 318.15) K

被引:7
作者
Chen, Jui-Tang [1 ]
Shiah, I-Min [1 ]
Chu, Hsiao-Pei [1 ]
机构
[1] Ming Hsin Univ Sci & Technol, Dept Chem Engn, Hsinchu 304, Hsin Feng, Taiwan
关键词
D O I
10.1021/je060288t
中图分类号
O414.1 [热力学];
学科分类号
摘要
Densities and viscosities at (298.15, 308.15, and 318.15) K are presented as a function of mixture composition for the binary mixtures of propylene glycol monomethyl ether with methacrylic acid, benzyl methacrylate, and 2-hydroxyethyl methacrylate. From the experimental data, the excess molar volumes and viscosity deviations have been calculated. These results have been correlated with the Redlich-Kister type polynomial to derive the coefficients and standard deviation. McAllister's three-body and four-body interaction models were also used to correlate the kinematic viscosities. These model's parameters were treated to be temperature-dependent.
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页码:2156 / 2160
页数:5
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