Corrosion behavior of copper T2 and brass H62 in simulated Nansha marine atmosphere

被引:48
作者
Lu, Xiao [1 ,2 ]
Liu, Yuwei [1 ,2 ]
Liu, Miaoran [2 ,3 ]
Wang, Zhenyao [1 ,2 ]
机构
[1] Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Liaoning, Peoples R China
[2] Chinese Acad Sci, Inst Met Res, Shenyang 110016, Liaoning, Peoples R China
[3] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
基金
中国国家自然科学基金;
关键词
Copper; Brass; Weight loss; Nansha; Atmospheric corrosion; DRY ATMOSPHERE; PRODUCTS; URBAN; HOT; MECHANISM; EVOLUTION; OUTDOOR; ALLOYS; TURPAN;
D O I
10.1016/j.jmst.2019.04.024
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The accelerated corrosion behavior of copper T2 and brass H62 exposed in simulated Nansha marine atmosphere for different periods were investigated by weight loss method, SEM. XRD and potentiodynamic polarization measurements. The results indicate that copper T2 and brass H62 underwent severe corrosion, and the final corrosion rates at 32 days of exposure were 0.24 mu m/d and 0.10 mu m/d, respectively. Moreover, the overall corrosion type of copper T2 was uniform and the corrosion products Cu2O and Cu2Cl(OH)(3) played a vital role in the corrosion rate of copper. While the dezincification corrosion with zinc preferential dissolution was obvious in brass H62. The predominant phases were the zinc-rich compounds Zn-5(OH)(8)Cl-2 center dot H2O, Zn-12(SO4)(3)Cl-3(OH)(15)center dot 5H(2)O and NaZn4(SO4)Cl(OH)(6)center dot 6H(2)O. There existed a large number of copper-rich holes with 20-50 pin depth beneath the corrosion product layer. (C) 2019 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.
引用
收藏
页码:1831 / 1839
页数:9
相关论文
共 32 条
[11]   A study of the evolution of rust on Mo-Cu-bearing fire-resistant steel submitted to simulated atmospheric corrosion [J].
Hao, Long ;
Zhang, Sixun ;
Dong, Junhua ;
Ke, Wei .
CORROSION SCIENCE, 2012, 54 :244-250
[12]   OXYGEN REDUCTION ON COPPER IN NEUTRAL NACL SOLUTION [J].
KING, F ;
QUINN, MJ ;
LITKE, CD .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1995, 385 (01) :45-55
[13]   Long-Term Corrosion of Copper in Hot and Dry Atmosphere in Turpan, China [J].
Kong, D. C. ;
Dong, C. F. ;
Fang, Y. H. ;
Xiao, K. ;
Guo, C. Y. ;
He, G. ;
Li, X. G. .
JOURNAL OF MATERIALS ENGINEERING AND PERFORMANCE, 2016, 25 (07) :2977-2984
[14]   Copper corrosion in hot and dry atmosphere environment in Turpan, China [J].
Kong, De-cheng ;
Dong, Chao-fang ;
Fang, Yue-hua ;
Xiao, Kui ;
Guo, Chun-yun ;
He, Gang ;
Li, Xiao-gang .
TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA, 2016, 26 (06) :1721-1728
[15]   Insight into the mechanism of alloying elements (Sn, Be) effect on copper corrosion during long-term degradation in harsh marine environment [J].
Kong, Decheng ;
Dong, Chaofang ;
Ni, Xiaoqing ;
Man, Cheng ;
Xiao, Kui ;
Li, Xiaogang .
APPLIED SURFACE SCIENCE, 2018, 455 :543-553
[16]   Corrosion behaviour of copper under chloride-containing thin electrolyte layer [J].
Liao, Xiaoning ;
Cao, Fahe ;
Zheng, Liyun ;
Liu, Wenjuan ;
Chen, Anna ;
Zhang, Jianqing ;
Cao, Chunan .
CORROSION SCIENCE, 2011, 53 (10) :3289-3298
[17]   The effect of β-FeOOH on the corrosion behavior of low carbon steel exposed in tropic marine environment [J].
Ma, Yuantai ;
Li, Ying ;
Wang, Fuhui .
MATERIALS CHEMISTRY AND PHYSICS, 2008, 112 (03) :844-852
[18]   THE CORROSION BEHAVIOR OF COPPER-ALLOYS, STAINLESS-STEELS AND TITANIUM IN SEAWATER [J].
MANSFELD, F ;
LIU, G ;
XIAO, H ;
TSAI, CH ;
LITTLE, BJ .
CORROSION SCIENCE, 1994, 36 (12) :2063-2095
[19]  
Mathiazhagan A, 2010, J MAR SCI TECH-TAIW, V18, P719
[20]   Outdoor and indoor atmospheric corrosion of non-ferrous metals [J].
Mendoza, AR ;
Corvo, F .
CORROSION SCIENCE, 2000, 42 (07) :1123-1147