Direct functionalization of benzylic C-Hs with vinyl acetates via Fe-catalysis

被引：101

作者：

Song, Chun-Xiao ^{[1
,2
]}

Cai, Gui-Xin ^{[1
,2
]}

Farrell, Thomas R. ^{[3
]}

Jiang, Zhong-Ping ^{[1
,2
]}

Li, Hu ^{[1
,2
]}

Gan, Liang-Bing ^{[1
,2
]}

Shi, Zhang-Jie ^{[1
,2
,4
]}

机构：

[1] Peking Univ, BNLMS, Beijing 100871, Peoples R China

[2] Peking Univ, Minist Educ, Key Lab Bioorgan Chem & Mol Engn, Beijing 100871, Peoples R China

[3] Univ Rochester, Dept Chem, Rochester, NY 14627 USA

[4] Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2009年 / 40期

基金：

美国国家科学基金会;

关键词：

CROSS-COUPLING REACTIONS; ALKYL-HALIDES; GRIGNARD-REAGENTS; AROMATIC-SUBSTITUTION; OXIDATIVE ACTIVATION; BOND ACTIVATION; ARYL IODIDES; IRON; ARYLATION; METAL;

D O I：

10.1039/b911031c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Direct cross-coupling to construct sp(3) C-sp(3) C bonds via Fe-catalyzed benzylic C-H activation with 1-aryl vinyl acetate was developed.

引用

页码：6002 / 6004

页数：3

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