Structural and electrochemical characterization of YBa(Fe,Co,Cu)2O5+δ layered perovskites as cathode materials for solid oxide fuel cells

被引：15
|
作者：
Klyndyuk, Andrei I. [1 ]
Mosialek, Michal [2 ]
Kharitonov, Dmitry S. [2 ]
Chizhova, Ekaterina A. [1 ]
Zimowska, Malgorzata [2 ]
Socha, Robert P. [2 ]
Komenda, Anna [3 ]
机构：
[1] Belarusian State Technol Univ, Sverdlova St 13A, Minsk 220006, BELARUS
[2] Polish Acad Sci, Jerzy Haber Inst Catalysis & Surface Chem, Niezapominajek 8, PL-30239 Krakow, Poland
[3] Res & Dev Ctr Technol Ind, Ludwika Warynskiego 3A, PL-00645 Warsaw, Poland
来源：
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2021年 / 46卷 / 32期
关键词：
Intermediate temperature solid oxide fuel cell; Cathode; Layered perovskites; Thermal expansion coefficient; Electrical properties; Electrochemical impedance spectroscopy; THERMAL-EXPANSION; OXYGEN REDUCTION; LNBAFECOO(5+DELTA) LN; TRANSPORT-PROPERTIES; PERFORMANCE; SUBSTITUTION; ND; YBACO2O5+DELTA; CO; SM;
D O I：
10.1016/j.ijhydene.2021.01.141
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Single- and double-doped YBa(Fe,Co,Cu)(2)O5+delta layered perovskites are prepared by solid state reaction method and their structural characteristics, thermal expansion coefficient, oxygen nonstoichiometry, electrical conductivity, and electrochemical performance are comparatively studied. The substitution of Co by Fe or/and Cu significantly improves thermal expansion properties as compared to undoped YBaCo2O5+delta. Electrochemical tests demonstrate the promising performance of synthesized materials as cathode materials at intermediate temperatures. Single doped YBaCuCoO5+delta cathodes reveal the lowest polarization resistance equal to 0.24 and 0.78 Omega cm(2) at P(O-2) P-1 = 0.2 at temperature of 800 and 700 degrees C, respectively. (C) 2021 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码：16977 / 16988
页数：12
相关论文
共 50 条
  • [1] Double substituted NdBa(Fe,Co,Cu)2O5+δ layered perovskites as cathode materials for intermediate-temperature solid oxide fuel cells-correlation between structure and electrochemical properties
    Klyndyuk, Andrei, I
    Kharytonau, Dzmitry S.
    Mosialek, Michal
    Chizhova, Ekaterina A.
    Komenda, Anna
    Socha, Robert P.
    Zimowska, Malgorzata
    ELECTROCHIMICA ACTA, 2022, 411
  • [2] Layered Oxygen-Deficient Double Perovskites as Promising Cathode Materials for Solid Oxide Fuel Cells
    Klyndyuk, Andrei I.
    Chizhova, Ekaterina A.
    Kharytonau, Dzmitry S.
    Medvedev, Dmitry A.
    MATERIALS, 2022, 15 (01)
  • [3] Electrochemical performance of Pr1-xYxBaCo2O5+δ layered perovskites as cathode materials for intermediate-temperature solid oxide fuel cells
    Zhao, Hailei
    Zheng, Yu
    Yang, Chunyang
    Shen, Yongna
    Du, Zhihong
    Swierczek, Konrad
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2013, 38 (36) : 16365 - 16372
  • [4] A Layered Perovskite EuBaCo2O5+δ for Intermediate-Temperature Solid Oxide Fuel Cell Cathode
    Shi, Z.
    Xia, T.
    Meng, F.
    Wang, J.
    Lian, J.
    Zhao, H.
    Bassat, J. -M.
    Grenier, J. -C.
    Meng, J.
    FUEL CELLS, 2014, 14 (06) : 979 - 990
  • [5] Synthesis and characterization of aluminum-doped perovskites as cathode materials for intermediate temperature solid oxide fuel cells
    Lou, Zhongliang
    Qiao, Jinshuo
    Yan, Yiming
    Peng, Jun
    Wang, Zhenhua
    Jiang, Taizhi
    Sun, Kening
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2012, 37 (15) : 11345 - 11350
  • [6] Ca and Fe co-doped NdBaCo2O5+δ double perovskites as high-performance cathodes for solid oxide fuel cells
    Chen, Mingcun
    Zhang, Haixia
    Yao, Chuangang
    Lou, Hao
    Xia, Baixi
    Zhang, Zhe
    Sun, Yuxi
    Lang, Xiaoshi
    Cai, Kedi
    JOURNAL OF ALLOYS AND COMPOUNDS, 2023, 968
  • [7] Effect of Fe doping on PrBaCo2O5+δ as cathode for intermediate-temperature solid oxide fuel cells
    Zou, Jing
    Park, Jungdeok
    Kwak, Buho
    Yoon, Heechul
    Chung, Jongshik
    SOLID STATE IONICS, 2012, 206 : 112 - 119
  • [8] Structural, thermal and electrochemical properties of layered perovskite SmBaCo2O5+d, a potential cathode material for intermediate-temperature solid oxide fuel cells
    Kim, Jung Hyun
    Kim, Yongmin
    Connor, Paul A.
    Irvine, John T. S.
    Bae, Joongmyeon
    Zhou, Wuzong
    JOURNAL OF POWER SOURCES, 2009, 194 (02) : 704 - 711
  • [9] Triple-Conducting Layered Perovskites as Cathode Materials for Proton-Conducting Solid Oxide Fuel Cells
    Kim, Junyoung
    Sengodan, Sivaprakash
    Kwon, Goeun
    Ding, Dong
    Shin, Jeeyoung
    Liu, Meilin
    Kim, Guntae
    CHEMSUSCHEM, 2014, 7 (10) : 2811 - 2815
  • [10] A novel layered perovskite electrode for symmetrical solid oxide fuel cells: PrBa(Fe0.8Sc0.2)2O5+δ
    He, Wei
    Wu, Xuelian
    Dong, Feifei
    Ni, Meng
    JOURNAL OF POWER SOURCES, 2017, 363 : 16 - 19
12345