Platinum-catalysed aerobic 1,2-aminooxygenation of alkenes

被引:70
作者
Muniz, Kilian [1 ]
Iglesias, Alvaro [1 ]
Fang, Yewen [1 ]
机构
[1] Univ Strasbourg, Inst Chim, UMR 7177, F-67000 Strasbourg, France
关键词
REDUCTIVE ELIMINATION; INTRAMOLECULAR DIAMINATION; BOND FORMATION; CARBON-CARBON; PT-IV; HYDROAMINATION; OXIDATION; COMPLEXES; AMINOACETOXYLATION; AMINOPALLADATION;
D O I
10.1039/b912139k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Platinum(II) salts in combination with copper salts and molecular oxygen catalyse an unprecedented intramolecular transfer of heteroatoms to alkenes to yield aminooxygenation products under sustainable conditions.
引用
收藏
页码:5591 / 5593
页数:3
相关论文
共 47 条
[1]   Palladium-catalyzed ring-forming aminoacetoxylation of alkenes [J].
Alexanian, EJ ;
Lee, C ;
Sorensen, EJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (21) :7690-7691
[2]   Platinum-catalyzed intramolecular hydroamination of unactivated olefins with secondary alkylamines [J].
Bender, CF ;
Widenhoefer, RA .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (04) :1070-1071
[3]   A NOVEL PTCL4-CATALYZED CYCLOREARRANGEMENT OF ALLYL PROPYNYL ETHERS TO 3-OXABICYCLO[4.1.0]HEPTENES [J].
BLUM, J ;
BEERKRAFT, H ;
BADRIEH, Y .
JOURNAL OF ORGANIC CHEMISTRY, 1995, 60 (17) :5567-5569
[4]  
Bolm C., 2000, CATALYTIC ASYMMETRIC, P299
[5]   Electrophilic activation of alkenes by platinum(II):: So much more than a slow version of palladium(II) [J].
Chianese, Anthony R. ;
Lee, Stephen J. ;
Gagne, Michel R. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (22) :4042-4059
[6]   Metal-Free Oxidative Cyclization of Urea-Tethered Alkenes with Hypervalent Iodine [J].
Cochran, Brian M. ;
Michael, Forrest E. .
ORGANIC LETTERS, 2008, 10 (21) :5039-5042
[7]   Construction of tetrahydrofurans by PdII/PdIV-catalyzed aminooxygenation of alkenes [J].
Desai, Lopa V. ;
Sanford, Melanie S. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (30) :5737-5740
[8]   PtCl4-catalyzed domino synthesis of fused bicyclic acetals [J].
Dieguez-Vazquez, Alejandro ;
Tzschucke, C. Christoph ;
Lam, Wing Yee ;
Ley, Steven V. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (01) :209-212
[9]   COMPETITIVE CARBON-CARBON REDUCTIVE ELIMINATION AND CARBON-IODIDE BOND FORMATION FROM A PT(IV) COMPLEX [J].
GOLDBERG, KI ;
YAN, JY ;
WINTER, EL .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (04) :1573-1574
[10]   ENERGETICS AND MECHANISMS OF CARBON-CARBON AND CARBON-IODIDE REDUCTIVE ELIMINATION FROM A PT(IV) CENTER [J].
GOLDBERG, KI ;
YAN, JY ;
BREITUNG, EM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (26) :6889-6896