The shortest C-H•••O hydrogen bonds yet determined by single crystal neutron diffraction:: a structural study of two phosphonium aryloxides

被引：26
作者：
Davidson, MG [1 ]
Goeta, AE
Howard, JAB
Lamb, S
Mason, SA
机构：
[1] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England
[2] Univ Durham, Dept Chem, Sci Labs, Durham DH1 3LE, England
[3] Inst Max Von Laue Paul Langevin, F-38042 Grenoble, France
来源：
NEW JOURNAL OF CHEMISTRY | 2000年 / 24卷 / 07期
关键词：
D O I：
10.1039/b001433h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The structures of two phosphonium aryloxides have been determined by neutron diffraction at 20 It and reveal extensive aggregation in the solid state via very short C-H ... O and C-H ...pi interactions, including the shortest C-H ... O distance yet determined by neutron diffraction.
引用
收藏
页码：477 / 479
页数：3
相关论文
共 16 条
[1]  
AAKEROY CB, 1993, CHEM SOC REV, P397
[2]   First neutron diffraction analysis of an O-H center dot center dot center dot pi hydrogen bond: 2-Ethynyladamantan-2-ol [J].
Allen, FH ;
Howard, JAK ;
Hoy, VJ ;
Desiraju, GR ;
Reddy, DS ;
Wilson, CC .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (17) :4081-4084
[3]  
ALLEN FH, 1993, CHEM DESIGN AUTOMATI, V8, P1
[4]   PROTONATION OF AN YLIDE LEADS TO A UNIQUE C-H-CENTER-DOT-CENTER-DOT-CENTER-DOT-O HYDROGEN-BONDED DIMER - THE FIRST SYNTHESIS, ISOLATION AND X-RAY STRUCTURAL CHARACTERIZATION OF A PHOSPHONIUM ARYLOXIDE [J].
DAVIDSON, MG .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (09) :919-920
[5]   The first structural characterisation of a phosphonium amide: synthesis, isolation and molecular structure of (Ph3PEt)(+)(NPh2)(-) [J].
Davidson, MG ;
Lamb, S .
POLYHEDRON, 1997, 16 (24) :4393-4395
[6]   Definitive crystal structures of ortho-, meta- and para-carboranes: Supramolecular structures directed solely by C-H center dot center dot center dot O hydrogen bonding to hmpa (hmpa equals hexamethylphosphoramide) [J].
Davidson, MG ;
Hibbert, TG ;
Howard, JAK ;
Mackinnon, A ;
Wade, K .
CHEMICAL COMMUNICATIONS, 1996, (19) :2285-2286
[7]   The first synthesis, isolation and x-ray structure of a phosphonium phosphide, (Ph3PMe)+{[C6H2(CF3)3-2,4,6]2P}- [J].
Davidson, MG ;
Dillon, KB ;
Howard, JAK ;
Lamb, S ;
Roden, MD .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1998, 550 (1-2) :481-484
[8]   THE C-H...O HYDROGEN-BOND IN CRYSTALS - WHAT IS IT [J].
DESIRAJU, GR .
ACCOUNTS OF CHEMICAL RESEARCH, 1991, 24 (10) :290-296
[9]   STRENGTH AND LINEARITY OF C-H=O BONDS IN MOLECULAR-CRYSTALS - A DATABASE STUDY OF SOME TERMINAL ALKYNES [J].
DESIRAJU, GR .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (06) :454-455
[10]  
DESIRAJU GR, 1995, ANGEW CHEM INT EDIT, V34, P2328
12