Applications of the [2,3]-Wittig rearrangement to total synthesis

被引：13

作者：

McGowan, G ^{[1
]}

机构：

[1] Univ Manchester, Dept Chem, Manchester M13 9PL, Lancs, England

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 2002年 / 55卷 / 12期

关键词：

D O I：

10.1071/CH02184

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The applications of [2,3]-Wittig rearrangement to total synthesis were analyzed. The [2,3]-Wittig rearrangement is a thermally allowed sigmatropic isomerization, initiated by the treatment of allylic ethers with suitable base. To introduce chirality into achiral molecules, a method was proposed known as asymmetric metallation which is deprotonation with a chiral non-racemic base.

引用

页码：799 / 799

页数：1

共 7 条

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