Charge transfer in intercalated C60 peapods

被引:0
|
作者
Pichler, T [1 ]
Kukovecz, A [1 ]
Kuzmany, H [1 ]
Kataura, H [1 ]
Achiba, Y [1 ]
机构
[1] Univ Vienna, Inst Mat Phys, A-1090 Vienna, Austria
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中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
We report on the charge transfer in intercalated C-60 peapods as a function of doping. A competition between a charge transfer to the SWCNT pods and one to the C60 peas is observed. At low intercalation levels the charge transfer is predominantly to the SWCNT pods. This leads to. a shift of the Fermi level beyond the third van Hove singularity of the semiconducting tubes for potassium intercalation (n-doping) and beyond the first singularity of the metallic tubes for FeCl3 intercalation (p-doping), respectively. In addition at high levels of potassium intercalation the C-60 pods are charged up to C-60(6-) and form a metallic one dimensional polymer.
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页码:118 / 122
页数:5
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