Nano TiO2 film electrode for electrocatalytic reduction of furfural in ionic liquids

被引：37

作者：

Chu, Daobao ^{[1
,2
]}

Hou, Yuanyuan ^{[1
]}

He, Jianguo ^{[1
]}

Xu, Mai ^{[1
]}

Wang, Yuqing ^{[1
]}

Wang, Shuxi ^{[1
]}

Wang, Jian ^{[1
]}

Zha, Longwu ^{[1
]}

机构：

[1] Anhui Normal Univ, Coll Chem & Mat Sci, Wuhu 241000, Anhui, Peoples R China

[2] Anhui Normal Univ, Anhui Key Lab Funct Mol Solids, Wuhu 241000, Anhui, Peoples R China

来源：

JOURNAL OF NANOPARTICLE RESEARCH | 2009年 / 11卷 / 07期

基金：

中国国家自然科学基金;

关键词：

Furfural; Furfuryl alcohol; Ionic liquids; Nanoporous TiO2 electrode; Electrocatalytic reduction; Sol-gel synthesis;

D O I：

10.1007/s11051-009-9610-5

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Nanoporous TiO2 having enhanced surface area was synthesized by sol-gel method. An "environmental friendly" method for production of furfuryl alcohol was presented by electrocatalytic reduction of furfural to furfuryl alcohol in ionic liquid medium at the surface of nanoporous TiO2 film electrode. The heterogeneous catalytic redox behaviour of a nanoporous TiO2 film electrode surface was investigated by cyclic voltammetry (CV). It was found that the catalytic reduction of furfural by Ti(IV)/Ti(III) redox system on the nanoporous TiO2 film surface. The electrode reaction mechanism is called catalytic (EC') mechanism, current density can reach 38 mA/cm(2) and yielding an overall conversion efficiency of 61.7%.

引用

页码：1805 / 1809

页数：5

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