Photochemical behaviour of fire-retarded polymers

被引：17
作者：
Chantegraille, Denis [1 ,2 ]
Morlat-Therias, Sandrine [1 ]
Gardette, Jean-Luc [1 ]
机构：
[1] Univ Blaise Pascal Clermont II, CNRS, UMR 6505, Photochim Mol & Macromol Lab, F-63170 Aubiere, France
[2] ZI Campine, ADDIPLAST, F-43620 St Pal De Mons, France
来源：
POLYMER DEGRADATION AND STABILITY | 2010年 / 95卷 / 03期
关键词：
Photodegradation; Fire-retardancy; Stabilisation; Durability; POLYPROPYLENE; PHOTOOXIDATION; MECHANISM; SYSTEMS; HALS;
D O I：
10.1016/j.polymdegradstab.2009.11.012
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The influence of a non-halogenated intumescent fire retardant on the photooxidation of polypropylene is reported The photooxidation of polypropylene stabilised with a phenolic antioxidant and two redox antioxidants (HALS), without and With the flame retardant has been studied The chemical modifications resulting from UV-light exposure with wavelengths above 300 nm in the presence of oxygen were followed by IR and UV-visible spectroscopies Special attention was given to the influence of each component on the rate of oxidation of the polymeric matrix The photooxidation of the fire-retarded polymer can be described by two independent phenomena the photooxidation of the intumescent agent and the photooxidation of the polymer The results obtained offer new insight in the formulation of stabilised fire-retarded PP for outdoors applications (c) 2009 Elsevier Ltd All rights reserved.
引用
收藏
页码：274 / 277
页数：4
相关论文
共 15 条
[1]   Intumescent flame retardant systems of modified rheology [J].
Anna, P ;
Marosi, G ;
Bourbigot, S ;
Le Bras, M ;
Delobel, R .
POLYMER DEGRADATION AND STABILITY, 2002, 77 (02) :243-247
[2]   Influence of aromatic brominated flame retardants on alkane photo-oxidation:: A model and polymer study [J].
Antos, K ;
Sedlár, J .
POLYMER DEGRADATION AND STABILITY, 2005, 90 (01) :180-187
[3]   STUDIES OF THE EFFECTS OF PHOSPHORUS NITROGEN BROMINE SYSTEMS ON THE COMBUSTION OF SOME THERMOPLASTIC POLYMERS [J].
CULLIS, CF ;
HIRSCHLER, MM ;
TAO, QM .
EUROPEAN POLYMER JOURNAL, 1991, 27 (03) :281-289
[4]   PHOTOOXIDATION OF UNSTABILIZED AND HALS-STABILIZED POLYPHASIC ETHYLENE-PROPYLENE POLYMERS [J].
DELPRAT, P ;
DUTEURTRE, X ;
GARDETTE, JL .
POLYMER DEGRADATION AND STABILITY, 1995, 50 (01) :1-12
[5]   Photooxidation of fire retarded polypropylene [J].
Gardette, JL ;
Sinturel, C ;
Lemaire, J .
POLYMER DEGRADATION AND STABILITY, 1999, 64 (03) :411-417
[6]   GAMMA-INITIATED, PHOTO-INITIATED, AND THERMALLY-INITIATED OXIDATION OF ISOTACTIC POLYPROPYLENE [J].
LACOSTE, J ;
VAILLANT, D ;
CARLSSON, DJ .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1993, 31 (03) :715-722
[7]   The influence of an N-alkoxy HALS on the decomposition of a brominated fire retardant in polypropylene [J].
Marney, D. C. O. ;
Russell, L. J. ;
Stark, T. M. .
POLYMER DEGRADATION AND STABILITY, 2008, 93 (03) :714-722
[8]   Influence of the exposure parameters on the mechanism of photooxidation of polypropylene [J].
Philippart, JL ;
Sinturel, C ;
Arnaud, R ;
Gardette, JL .
POLYMER DEGRADATION AND STABILITY, 1999, 64 (02) :213-225
[9]   MASS-SPECTROSCOPY ANALYSIS OF VOLATILE PHOTOPRODUCTS IN PHOTOOXIDATION OF POLYPROPYLENE [J].
PHILIPPART, JL ;
POSADA, F ;
GARDETTE, JL .
POLYMER DEGRADATION AND STABILITY, 1995, 49 (02) :285-290
[10]   Influence of light intensity on the photooxidation of polypropylene [J].
Philippart, JL ;
Sinturel, C ;
Gardette, JL .
POLYMER DEGRADATION AND STABILITY, 1997, 58 (03) :261-268
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