Influence of Temperature and Composition upon Density, Viscosity, Speed of Sound, and Refractive Index of Aqueous Solutions of 1-Ethyl-2-pyrrolidinone

被引:22
作者
Blanco, Antonio
Garcia-Abuin, Alicia
Gomez-Diaz, Diego
Navaza, Jose M. [1 ]
Vidal-Tato, Isabel
机构
[1] Univ Santiago de Compostela, ETSE, Dept Chem Engn, PF&PT Team, E-15782 Santiago De Compostela, Galicia, Spain
关键词
DEGREES-C; LIQUID; SYSTEM; PYRROLIDINE; PIPERIDINE; SOLVENTS; BINARY;
D O I
10.1021/je9003959
中图分类号
O414.1 [热力学];
学科分类号
摘要
Experimental density, viscosity, speed of sound, and refractive index for aqueous solutions of 1-ethyl-2-pyrrolidinone were measured over the entire composition range and at different temperatures (293 to 323) K. Excess properties and deviations have been calculated, and their dependence on composition was mathematically represented by a Redlich-Kister-type equation. The hydration of pyrrolidinone molecules plays an important role in the thermophysical behavior of this mixture.
引用
收藏
页码:962 / 965
页数:4
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