Synthesis of dicationic symmetrical and asymmetrical ionic liquids and their tribological properties as ultrathin films

被引：100
作者：
Yu, Guiqin
Yan, Shiqiang
Zhou, Feng
Liu, Xuqing
Liu, Weimin
Liang, Yongmin [1 ]
机构：
[1] Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China
[2] Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China
来源：
TRIBOLOGY LETTERS | 2007年 / 25卷 / 03期
基金：
中国国家自然科学基金;
关键词：
solid lubrication; film thickness; thermal stability; steel; SEM; EDS;
D O I：
10.1007/s11249-006-9167-8
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
A new series of novel dicationic symmetrical and asymmetrical ionic liquids (ILs) consisting of tributylalkyl phosphonium and alkylimidazolium were synthesized. Their tribological properties in the form of spin-coated ultra-thin films sliding against AISI-52100 steel ball were studied in a ball-on-plate configuration on a Universal Micro-tribometer-2MT tester, using perfluoropolyether (PFPE) and normal ILs as comparisons. The best result is obtained for asymmetrical 1-(1-tributylphosphine-yl-hexyl)-3methylimidazolium dihexafluorophosphate, which has very high decomposition temperature-about 450 degrees C and good tribological properties.
引用
收藏
页码：197 / 205
页数：9
相关论文
共 46 条
  • [1] Synthesis of dicationic symmetrical and asymmetrical ionic liquids and their tribological properties as ultrathin films
    Guiqin Yu
    Shiqiang Yan
    Feng Zhou
    Xuqing Liu
    Weimin Liu
    Yongmin Liang
    Tribology Letters, 2007, 25 : 197 - 205
  • [2] Synthesis and properties of dicationic ionic liquids with pentasiloxane linker
    Krasovskiy, Vladimir G.
    Gorbatsevich, Olga B.
    Talalaeva, Evgenia V.
    Glukhov, Lev M.
    Chernikova, Elena A.
    Kustov, Leonid M.
    MENDELEEV COMMUNICATIONS, 2022, 32 (04) : 551 - 553
  • [3] Properties of Dicationic Disiloxane Ionic Liquids
    Krasovskiy, Vladimir G.
    Kapustin, Gennady I.
    Gorbatsevich, Olga B.
    Glukhov, Lev M.
    Chernikova, Elena A.
    Koroteev, Anatoly A.
    Kustov, Leonid M.
    MOLECULES, 2020, 25 (12):
  • [4] Systematic Synthesis and Properties Evaluation of Dicationic Ionic Liquids, and a Glance Into a Potential New Field
    Guglielmero, Luca
    Mezzetta, Andrea
    Guazzelli, Lorenzo
    Pomelli, Christian S.
    D'Andrea, Felicia
    Chiappe, Cinzia
    FRONTIERS IN CHEMISTRY, 2018, 6
  • [5] Physicochemical properties of branched-chain dicationic ionic liquids
    Talebi, Mohsen
    Patil, Rahul A.
    Armstrong, Daniel W.
    JOURNAL OF MOLECULAR LIQUIDS, 2018, 256 : 247 - 255
  • [6] Tribological properties of ionic liquids as new lubricants
    Kamimura, H
    Minami, I
    Mori, S
    JOURNAL OF JAPANESE SOCIETY OF TRIBOLOGISTS, 2005, 50 (03) : 208 - 213
  • [7] Synthesis and characterization of dicationic ionic liquids that contain both hydrophilic and hydrophobic anions
    Chang, Jui-Cheng
    Ho, Wen-Yueh
    Sun, I-Wen
    Tung, Yung-Liang
    Tsui, Meng-Chin
    Wu, Tzi-Yi
    Liang, Shih-Shin
    TETRAHEDRON, 2010, 66 (32) : 6150 - 6155
  • [8] Recent progress on phosphonium-based room temperature ionic liquids: Synthesis, properties, tribological performances and applications
    Rahman, Md Hafizur
    Khajeh, Arash
    Panwar, Pawan
    Patel, Manish
    Martini, Ashlie
    Menezes, Pradeep L.
    TRIBOLOGY INTERNATIONAL, 2022, 167
  • [9] Synthesis and Properties of Hydroxyl-Containing Ionic Liquids
    Krasovskiy, V. G.
    Chernikova, E. A.
    Glukhov, L. M.
    Kapustin, G. I.
    Koroteev, A. A.
    Kustov, L. M.
    RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2018, 54 (01) : 143 - 145
  • [10] Synthesis of Functionalized Ionic Liquids Based on Benzimidazolium and Their Properties
    Wang Bin
    Liu Chen-Jiang
    Wang Ji-De
    Lei Zhen-Kai
    Hu Dong-Lin
    CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2012, 33 (01): : 76 - 81
12345