Coordination polymers: Structural transformation from two to three dimensions through ligand conformation change

被引：112
作者：
Shi, Z [1 ]
Zhang, LR [1 ]
Gao, S [1 ]
Yang, GY [1 ]
Hua, J [1 ]
Gao, L [1 ]
Feng, SH [1 ]
机构：
[1] Jilin Univ, Key Lab Inorgan Synthesis & Preparat Chem, Changchun 130023, Peoples R China
来源：
INORGANIC CHEMISTRY | 2000年 / 39卷 / 09期
关键词：
D O I：
10.1021/ic991355q
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two coordination polymers of {[Mn(maleate)(μ-4,4'-bipy)]·0.5(H2O)}∞ (1) and {[Mn(fumarate)(μ-4,4'-bipy)(H2O)]·0.5(4,4'-bipy)}∞ (2) (bipy = bipyridine) were synthesized and structurally characterized. The 1-D [Mn(maleate)]8 chains were formed by maleate molecules chelating Mn atoms, and these chains were connected with 4,4'-bipy to form a 2-D structure (structure 1). The 2-D [Mn(fumarate)(H2O)]∞ layers were composed of the fumarate molecules coordinating different Mn ions, and these layers were linked with 4,4'-bipy to give a 3-D open framework (structure 2).
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页码：1990 / 1993
页数：4
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