Recent Advances in Metal Catalyst Design for CO2 Hydroboration to C1 Derivatives

被引：36

作者：

Kostera, Sylwia ^{[1
]}

Peruzzini, Maurizio ^{[1
]}

Gonsalvi, Luca ^{[1
]}

机构：

[1] CNR, Ist Chim Composti Organometallici ICCOM, Via Madonna Piano 10, I-50019 Florence, Italy

来源：

CATALYSTS | 2021年 / 11卷 / 01期

关键词：

carbon dioxide conversion; hydroboration; homogeneous catalysis; metal complexes;

D O I：

10.3390/catal11010058

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The use of CO2 as a C1 building block for chemical synthesis is receiving growing attention, due to the potential of this simple molecule as an abundant and cheap renewable feedstock. Among the possible reductants used in the literature to bring about CO2 reduction to C1 derivatives, hydroboranes have found various applications, in the presence of suitable homogenous catalysts. The current minireview article summarizes the main results obtained since 2016 in the synthetic design of main group, first and second row transition metals for use as catalysts for CO2 hydroboration.

引用

页码：1 / 26

页数：26

共 54 条

[21] Metathesis reactivity of bis(phosphinite) pincer ligated nickel chloride, isothiocyanate and azide complexes [J].

Li, Huizhen ;

Meng, Wenjuan ;

Adhikary, Anubendu ;

Li, Shujun ;

Ma, Nana ;

Zhao, Qianyi ;

Yang, Qiuyu ;

Eberhardt, Nathan A. ;

Leahy, Kendra M. ;

Krause, Jeanette A. ;

Zhang, Jie ;

Chen, Xuenian ;

Guan, Hairong .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2016, 804 :132-141

[22] A Hydride-Shuttle Mechanism for the Catalytic Hydroboration of CO2 [J].

Li, Longfei ;

Zhu, Huajie ;

Liu, Li ;

Song, Datong ;

Lei, Ming .

INORGANIC CHEMISTRY, 2018, 57 (06) :3054-3060

[23] Trapping a Silicon(I) Radical with Carbenes: A Cationic cAAC-Silicon(I) Radical and an NHC-Parent-Silyliumylidene Cation [J].

Li, Yan ;

Chan, Yuk-Chi ;

Leong, Bi-Xiang ;

Li, Yongxin ;

Richards, Emma ;

Purushothaman, Indu ;

De, Susmita ;

Parameswaran, Pattiyil ;

So, Cheuk-Wai .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2017, 56 (26) :7573-7578

[24] Hydroboration of CO2 catalyzed by bis(phosphinite) pincer ligated nickel thiolate complexes [J].

Liu, Ting ;

Meng, Wenjuan ;

Ma, Qiang-Qiang ;

Zhang, Jie ;

Li, Huizhen ;

Li, Shujun ;

Zhao, Qianyi ;

Chen, Xuenian .

DALTON TRANSACTIONS, 2017, 46 (14) :4504-4509

[25] Highly efficient reduction of carbon dioxide with a borane catalyzed by bis(phosphinite) pincer ligated palladium thiolate complexes [J].

Ma, Qiang-Qiang ;

Liu, Ting ;

Li, Shujun ;

Zhang, Jie ;

Chen, Xuenian ;

Guan, Hairong .

CHEMICAL COMMUNICATIONS, 2016, 52 (99) :14262-14265

[26] Divergent Coupling of Alcohols and Amines Catalyzed by Isoelectronic Hydride MnI and FeII PNP Pincer Complexes [J].

Mastalir, Matthias ;

Glatz, Mathias ;

Gorgas, Nikolaus ;

Stoeger, Berthold ;

Pittenauer, Ernst ;

Allmaier, Guenter ;

Veiros, Luis F. ;

Kirchner, Karl .

CHEMISTRY-A EUROPEAN JOURNAL, 2016, 22 (35) :12316-12320

[27] Synthesis and Reactivity of Nickel and Palladium Fluoride Complexes with PCP Pincer Ligands. NMR-Based Assessment of Electron-Donating Properties of Fluoride and Other Monoanionic Ligands [J].

Miguel Martinez-Prieto, Luis ;

Melero, Cristobal ;

del Rio, Diego ;

Palma, Pilar ;

Campora, Juan ;

Alvarez, Eleuterio .

ORGANOMETALLICS, 2012, 31 (04) :1425-1438

[28] New Feedstocks and Chemistry for Lower CO2-Footprint: Today, Tomorrow, and in the Future [J].

Mleczko, Leslaw ;

Wolf, Aurel ;

Lolli, Giulio .

CHEMBIOENG REVIEWS, 2016, 3 (05) :204-218

[29] Catalytic reduction of CO2into fuels and fine chemicals [J].

Modak, Arindam ;

Bhanja, Piyali ;

Dutta, Saikat ;

Chowdhury, Biswajit ;

Bhaumik, Asim .

GREEN CHEMISTRY, 2020, 22 (13) :4002-4033

[30] TRANSITION METAL-CARBON BONDS .42. COMPLEXES OF NICKEL, PALLADIUM, PLATINUM, RHODIUM AND IRIDIUM WITH TRIDENTATE LIGAND 2,6-BIS[(DI-T-BUTYLPHOSPHINO)METHYL]PHENYL [J].

MOULTON, CJ ;

SHAW, BL .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1976, (11) :1020-1024

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