Recent Advances in Metal Catalyst Design for CO2 Hydroboration to C1 Derivatives

被引:36
作者
Kostera, Sylwia [1 ]
Peruzzini, Maurizio [1 ]
Gonsalvi, Luca [1 ]
机构
[1] CNR, Ist Chim Composti Organometallici ICCOM, Via Madonna Piano 10, I-50019 Florence, Italy
关键词
carbon dioxide conversion; hydroboration; homogeneous catalysis; metal complexes;
D O I
10.3390/catal11010058
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The use of CO2 as a C1 building block for chemical synthesis is receiving growing attention, due to the potential of this simple molecule as an abundant and cheap renewable feedstock. Among the possible reductants used in the literature to bring about CO2 reduction to C1 derivatives, hydroboranes have found various applications, in the presence of suitable homogenous catalysts. The current minireview article summarizes the main results obtained since 2016 in the synthetic design of main group, first and second row transition metals for use as catalysts for CO2 hydroboration.
引用
收藏
页码:1 / 26
页数:26
相关论文
共 54 条
[1]   Complexes of the tripodal phosphine ligands PhSi(XPPh2)3 (X = CH2, O): synthesis, structure and catalytic activity in the hydroboration of CO2 [J].
Aloisi, Alicia ;
Berthet, Jean-Claude ;
Genre, Caroline ;
Thuery, Pierre ;
Cantat, Thibault .
DALTON TRANSACTIONS, 2016, 45 (37) :14774-14788
[2]   Utilisation of CO2 as a chemical feedstock:: opportunities and challenges [J].
Aresta, Michele ;
Dibenedetto, Angela .
DALTON TRANSACTIONS, 2007, (28) :2975-2992
[3]   Catalysis for the Valorization of Exhaust Carbon: from CO2 to Chemicals, Materials, and Fuels. Technological Use of CO2 [J].
Aresta, Michele ;
Dibenedetto, Angela ;
Angelini, Antonella .
CHEMICAL REVIEWS, 2014, 114 (03) :1709-1742
[4]   Boron-mediated activation of carbon dioxide [J].
Bontemps, Sebastien .
COORDINATION CHEMISTRY REVIEWS, 2016, 308 :117-130
[5]   Synthesis, Characterization, and Reactivity of Nickel Hydride Complexes Containing 2,6-C6H3(CH2PR2)2 (R = tBu, cHex, and iPr) Pincer Ligands [J].
Boro, Brian J. ;
Duesler, Eileen N. ;
Goldberg, Karen I. ;
Kemp, Richard A. .
INORGANIC CHEMISTRY, 2009, 48 (12) :5081-5087
[6]   Magnesium-catalyzed hydroboration of organic carbonates, carbon dioxide and esters [J].
Cao, Xu ;
Wang, Weifan ;
Lu, Kai ;
Yao, Weiwei ;
Xue, Fei ;
Ma, Mengtao .
DALTON TRANSACTIONS, 2020, 49 (09) :2776-2780
[7]   Recent Developments on the Use of Group 13 Metal Complexes in Catalysis [J].
Dagorne, Samuel ;
Wehmschulte, Rudolf .
CHEMCATCHEM, 2018, 10 (12) :2509-2520
[8]   A Disquisition on the Active Sites of Heterogeneous Catalysts for Electrochemical Reduction of CO2 to Value-Added Chemicals and Fuel [J].
Daiyan, Rahman ;
Saputera, Wibawa Hendra ;
Masood, Hassan ;
Leverett, Josh ;
Lu, Xunyu ;
Amal, Rose .
ADVANCED ENERGY MATERIALS, 2020, 10 (11)
[9]  
Desmons S., 2019, J VIS EXP, V153
[10]   Manganese-catalyzed hydroboration of carbon dioxide and other challenging carbonyl groups [J].
Erken, Christina ;
Kaithal, Akash ;
Sen, Suman ;
Weyhermueller, Thomas ;
Hoelscher, Markus ;
Werle, Christophe ;
Leitner, Walter .
NATURE COMMUNICATIONS, 2018, 9