Synthesis and electrochemistry of a substituted phthalocyaninatozinc

被引：15
|
作者：
Ma, Chunyu
Du, Guotong [1 ]
Cao, Yong
Yu, Shukun
Cheng, Chuanhui
Jiang, Wenhai
Chang, Yuchun
Wang, Xu
Cong, Fangdi
Yu, Haifeng
机构：
[1] Dalian Univ Technol, Dept Phys, State Key Lab Mat Modificat Laser Ion & Electron, Dalian 116023, Peoples R China
[2] Jilin Univ, State Key Lab Integrated Optoelect, Changchun 130012, Peoples R China
[3] NE Normal Univ, Fac Chem, Changchun 130024, Peoples R China
来源：
DYES AND PIGMENTS | 2007年 / 72卷 / 02期
基金：
中国国家自然科学基金;
关键词：
phthalocyanine; dye; synthesis; phenoxyl; electrochemistry; cyclic voltammetry;
D O I：
10.1016/j.dyepig.2005.08.024
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
The synthesis of a zinc phthalocyanine (Pc) bearing four phenoxyl substituents was described and its molecular structure was fully characterized by H-1 NMR, MS, elemental analysis, UV-vis and IR, which were consistent with the proposed structure. This Pc possesses excellent solubility in polar organic solvents, such as dichloromethane and THF, and doesn't readily aggregate to the dimer. TOF-MS and elemental analysis prove its excellent purity. The compound's electrochemical redox reactions in THF occurred in the Pc ring and were quasi-reversible single-electron processes. The electrochemical reaction mechanism was proposed. (c) 2005 Elsevier Ltd. All rights reserved.
引用
收藏
页码：267 / 270
页数：4
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