Optical properties of amorphous organo-modified silica nanoparticles produced via co-condensation method

被引:44
作者
Jafarzadeh, M. [2 ]
Rahman, I. A. [1 ]
Sipaut, C. S. [2 ]
机构
[1] Univ Sains Malaysia, Sch Dent Sci, Kubang Kerian 16150, Kelantan, Malaysia
[2] Univ Sains Malaysia, Sch Chem Sci, George Town 11800, Malaysia
关键词
Amorphous silica; Nanoparticles; Co-condensation; Photoluminescence; Optical absorption; PHOTOLUMINESCENCE CHARACTERIZATION; SIO2; MECHANISM; DEFECT; ABSORPTION; NANOWIRES; BANDS;
D O I
10.1016/j.ceramint.2009.09.010
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Structural defects in amorphous organo-modified silica nanoparticle have been studied via optical absorption and photoluminescence. The defect center, E', oxygen defect center (ODCs), self-trapped exciton, OH-related surface defect, hydrogen-related species and carbon-related species were found in the amino-functionalized modified silica. These interesting emitting surface centers were observed in the range of vacuum ultraviolet (VUV), UV-vis and near-IR. Raman results were also demonstrated transverse- and longitudinal-optical pairs due to the surface defect-related optical properties. (C) 2009 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
引用
收藏
页码:333 / 338
页数:6
相关论文
共 35 条
[11]  
Griscom D. L, 1991, J CERAM SOC JPN, V99, P923
[12]   Intense ultraviolet and green photoluminescence from sol-gel derived silica containing hydrogenated carbon [J].
He, HP ;
Wang, YX ;
Tang, HG .
JOURNAL OF PHYSICS-CONDENSED MATTER, 2002, 14 (45) :11867-11874
[13]   Photoluminescence properties of silica monoliths codoped with terbium and germanium [J].
Hernandez, I. ;
Cordoba, G. ;
Padilla, J. ;
Mendez-Vivar, J. ;
Arroyo, R. .
MATERIALS LETTERS, 2008, 62 (12-13) :1945-1948
[14]   OPTICAL STUDIES OF SELF-TRAPPED EXCITONS IN SIO2 [J].
ITOH, C ;
TANIMURA, K ;
ITOH, N .
JOURNAL OF PHYSICS C-SOLID STATE PHYSICS, 1988, 21 (26) :4693-4702
[15]   Synthesis of silica nanoparticles by modified sol-gel process: the effect of mixing modes of the reactants and drying techniques [J].
Jafarzadeh, M. ;
Rahman, I. A. ;
Sipaut, C. S. .
JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 2009, 50 (03) :328-336
[16]   Enhanced blue photoluminescence from SiCl4-treated nanometer-sized silica particles [J].
Kurumoto, Naoko ;
Yamada, Tomoko ;
Uchino, Takashi .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 2007, 353 (5-7) :684-686
[17]   Dense electronic excitation induced defects in fused silica [J].
Mohanty, T ;
Mishra, NC ;
Bhat, SV ;
Basu, PK ;
Kanjilal, D .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2003, 36 (24) :3151-3155
[18]   Photoluminescence of zinc oxide supported on submicron silica particles [J].
Neves, MC ;
Trindade, T ;
Peres, M ;
Wang, J ;
Soares, MJ ;
Neves, A ;
Monteiro, T .
MATERIALS SCIENCE & ENGINEERING C-BIOMIMETIC AND SUPRAMOLECULAR SYSTEMS, 2005, 25 (5-8) :654-657
[19]   Optical absorption and nonradiative decay mechanism of E′ center in silica [J].
Pacchioni, G ;
Ierano, G ;
Marquez, AM .
PHYSICAL REVIEW LETTERS, 1998, 81 (02) :377-380
[20]   STRUCTURAL MODEL OF RAMAN DEFECT BANDS OF VITREOUS SILICA [J].
PHILLIPS, JC .
PHYSICAL REVIEW B, 1987, 35 (12) :6409-6413