Optical properties of amorphous organo-modified silica nanoparticles produced via co-condensation method

被引:44
作者
Jafarzadeh, M. [2 ]
Rahman, I. A. [1 ]
Sipaut, C. S. [2 ]
机构
[1] Univ Sains Malaysia, Sch Dent Sci, Kubang Kerian 16150, Kelantan, Malaysia
[2] Univ Sains Malaysia, Sch Chem Sci, George Town 11800, Malaysia
关键词
Amorphous silica; Nanoparticles; Co-condensation; Photoluminescence; Optical absorption; PHOTOLUMINESCENCE CHARACTERIZATION; SIO2; MECHANISM; DEFECT; ABSORPTION; NANOWIRES; BANDS;
D O I
10.1016/j.ceramint.2009.09.010
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Structural defects in amorphous organo-modified silica nanoparticle have been studied via optical absorption and photoluminescence. The defect center, E', oxygen defect center (ODCs), self-trapped exciton, OH-related surface defect, hydrogen-related species and carbon-related species were found in the amino-functionalized modified silica. These interesting emitting surface centers were observed in the range of vacuum ultraviolet (VUV), UV-vis and near-IR. Raman results were also demonstrated transverse- and longitudinal-optical pairs due to the surface defect-related optical properties. (C) 2009 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
引用
收藏
页码:333 / 338
页数:6
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