Kinetics of the thermal decomposition of intercalation compounds during exfoliation

被引：7

作者：

Ren Hui

Kang Fei-yu ^{[1
]}

Jiao Qing-jie

Cui Qing-zhong

机构：

[1] Tsing Hua Univ, Grad Sch Shenzhen, Shenzhen 518055, Peoples R China

[2] Beijing Inst Technol, Natl Key Lab Explos Sci & Technol, Beijing 100081, Peoples R China

来源：

NEW CARBON MATERIALS | 2006年 / 21卷 / 04期

关键词：

exfoliation; thermal analysis; kinetics; intercalation;

D O I：

10.1016/S1872-5805(07)60003-1

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The phase transformations and thermal decomposition of the following graphite intercalation compounds (GICs), HNO3-CH3COOH-GIC, H2SO4-GIC and H2SO4-CH3COOH-GIC, were measured by an FTIR-associated TG apparatus. Using Kissinger and Ozawa principles, the kinetic parameters of some typical exfoliation reactions were evaluated and the thermal decomposition mechanism of the exfoliation process was determined. When the heating rate was in the range of 20-80 degrees C/min, the activation energies of the exfoliation reactions were all less than 120 kJ/mol.

引用

页码：315 / 319

页数：5

共 19 条

[1] Modelling of exfoliated graphite [J].

Celzard, A ;

Marêché, JF ;

Furdin, G .

PROGRESS IN MATERIALS SCIENCE, 2005, 50 (01) :93-179

[2] Review graphite [J].

Chung, DDL .

JOURNAL OF MATERIALS SCIENCE, 2002, 37 (08) :1475-1489

[3]

Gao L, 2006, NEW CARBON MATER, V21, P139

[4]

Gao L, 2006, NEW CARBON MATER, V21, P253

[5]

HONG RZ, 2001, THERMOANALYSIS KINET

[6]

HUANG DR, 1997, INFRARED RAMAN SPECT

[7] ROOM-TEMPERATURE EXFOLIATION OF GRAPHITE UNDER MICROGRAVITY [J].

INAGAKI, M ;

NAKASHIMA, M ;

SONEDA, Y ;

OKUTANI, T ;

SUZUKI, M ;

NAKATA, Y ;

NAGAI, H .

CARBON, 1993, 31 (08) :1349-1350

[8]

Inagaki M, 2003, NEW CARBON MATER, V18, P241

[9] Electrochemical synthesis and characterization of formic acid graphite intercalation compound [J].

Kang, F ;

Leng, Y ;

Zhang, TY .

CARBON, 1997, 35 (08) :1089-1096

[10]

KANG FY, 2000, NEW CARBON MATER, V15, P80

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