Unsymmetrical single-component nickel 1,2-dithiolene complexes with extended tetrachalcogenafulvalenedithiolato ligands

被引：15

作者：

Anyfantis, George C.

Papavassiliou, George C.

Aloukos, Panagiotis

Couris, Stelios

Weng, Yufeng F.

Yoshino, Harukazu

Murata, Keizo

机构：

[1] Natl Hellen Res Fdn, Inst Theoret & Phys Chem, GR-11635 Athens, Greece

[2] Fdn Res & Technol Hellas, Inst Chem Engn & High Temp Chem Proc, Patras 26504, Greece

[3] Univ Patras, Dept Phys, Patras 26504, Greece

[4] Osaka City Univ, Grad Sch Sci, Sumiyoshi Ku, Osaka 5588585, Japan

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2007年 / 62卷 / 02期

关键词：

metal 1,2-dithiolenes; nonlinear optics; organic semiconductors;

D O I：

10.1515/znb-2007-0209

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The unsymmetrical complexes Ni(dmdt)(dmio) and Ni(dmstfdt)(dmio) (dmdt = dimethyltetrathiafulvalenedithiolate, dmstfdt = dimethyldiselenadithiafulvalenedithiolate, dmio = 1,3-dithiol-2-one-4,5-dithiolate) were prepared and characterized analytically and spectroscopically. The complexes exhibit strong third-order nonlinear optical response in the visible and near-infrared spectral regions.

引用

页码：200 / 204

页数：5

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