Some physical properties of Sn-doped CdO thin films prepared by chemical bath deposition

被引:127
作者
de Leon-Gutierrez, L. R.
Cayente-Romero, J. J.
Peza-Tapia, J. M.
Barrera-Calva, E. [1 ]
Martinez-Flores, J. C.
Ortega-Lopez, M.
机构
[1] Univ Autonoma Metropolitana, CBI, IPH, Area Ingn Energia, Mexico City 09340, DF, Mexico
[2] IPN, CINVESTAV, Dept Ingn Elect, Secc Elect Estado Solido, Mexico City 07360, DF, Mexico
关键词
solar cells materials; chemical bath deposition; cadmium oxide; thin films;
D O I
10.1016/j.matlet.2006.03.131
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Undoped and Sn-doped CdO thin films were prepared by the chemical bath deposition method by means of a procedure that improves the deposition efficiency. All as-grown films were crystallized in the cubic structure of cadmium peroxide (CdO2) and transformed into CdO with a cubic structure after an annealing process. The as-grown films have a high resistivity (> 10(6) Omega cm) and an optical bandgap around 3.6 eV Undoped CdO displays an optical bandgap around 2.32-2.54 eV and has an electrical conductivity of g x 10(-4) Omega cm. The Sn incorporation into CdO produces a blue shift in the optical bandgap (from 2.55 to 2.84 eV) and a decrease in the electrical conductivity. The deposition procedure described here gives colloid-free surface thin films as indicated by the surface morphology analysis. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:3866 / 3870
页数:5
相关论文
共 16 条
[1]   Novel approach to the chemical bath deposition of chalcogenide semiconductors [J].
Boyle, DS ;
Bayer, A ;
Heinrich, MR ;
Robbe, O ;
O'Brien, P .
THIN SOLID FILMS, 2000, 361 :150-154
[2]   High transmittance CdO thin films obtained by the sol-gel method [J].
Carballeda-Galicia, DM ;
Castanedo-Pérez, R ;
Jiménez-Sandoval, O ;
Jiménez-Sandoval, S ;
Torres-Delgado, G ;
Zúñiga-Romero, CI .
THIN SOLID FILMS, 2000, 371 (1-2) :105-108
[3]   DEGENERATE CADMIUM-OXIDE FILMS FOR ELECTRONIC DEVICES [J].
CHU, TL ;
CHU, SS .
JOURNAL OF ELECTRONIC MATERIALS, 1990, 19 (09) :1003-1005
[4]   Some physical properties of F-doped CdO thin films deposited by spray pyrolysis [J].
Ferro, R ;
Rodríguez, JA .
THIN SOLID FILMS, 1999, 347 (1-2) :295-298
[5]   PHASE-FORMATION PROCESSES IN SOLUTION AT THE ATOMIC-LEVEL - METAL CHALCOGENIDE SEMICONDUCTORS [J].
FROMENT, M ;
LINCOT, D .
ELECTROCHIMICA ACTA, 1995, 40 (10) :1293-1303
[6]   Chemical deposition method for metal chalcogenide thin films [J].
Mane, RS ;
Lokhande, CD .
MATERIALS CHEMISTRY AND PHYSICS, 2000, 65 (01) :1-31
[7]   Cadmium sulphide growth investigations on different SnO2 substrates [J].
Martínez, MA ;
Guillén, C ;
Herrero, J .
APPLIED SURFACE SCIENCE, 1999, 140 (1-2) :182-189
[8]   High rate deposition of transparent conducting oxide thin films by vacuum arc plasma evaporation [J].
Minami, T ;
Ida, S ;
Miyata, T .
THIN SOLID FILMS, 2002, 416 (1-2) :92-96
[9]   CHEMICALLY DEPOSITED N-CDO THIN-FILMS FOR SOLAR-CELL APPLICATION [J].
OCAMPO, M ;
SEBASTIAN, PJ ;
CAMPOS, J .
PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE, 1994, 143 (01) :K29-K32
[10]   Improved efficiency of the chemical bath deposition method during growth of ZnO thin films [J].
Ortega-López, M ;
Avila-García, A ;
Albor-Aguilera, ML ;
Sánchez-Resendiz, VM .
MATERIALS RESEARCH BULLETIN, 2003, 38 (07) :1241-1248