Ultrasonic synthesis of two nanostructured cadmium(II) coordination supramolecular polymers: Solvent influence, luminescence and photocatalytic properties

Two nanoparticles of cadmium(II) coordination polymers (CPs) formulated as [Cd(L)(DCTP)](n) (1) and [Cd(L)(2)(DCTP)center dot 2H(2)O](n) (2) (L = 1,2-bis(2-methylbenzimidazol-1-ylmethyl)benzene, H2DCTP = 2,5-dichloroterephthalic acid) were prepared by the sonochemical approach in different solvents and characterized by elemental analysis, IR spectra, scanning electron microscopy (SEM), and powder X-ray diffraction. Structural determination reveals that CP 1 displays a 2D four-connected sql net layer, Whilst CP 2 exhibits a 1D "V"-like chain structure. Luminescence properties, thermal behavior, and photocatalytic activities of the nanoparticles of CPs 1 and 2 on the degradation of methylene blue were investigated. The photocatalytic mechanism is carried out by introducing t-butyl alcohol (TBA) as a widely used (OH)-O-center dot scavenger. Furthermore, the influence of solvents, reaction time, and ultrasound irradiation temperature on the morphology and size of the nanostructure CPs 1 and 2 were investigated. The results indicated that an increase of time and ultrasound irradiation temperature decreased the nanostructured size. (C) 2017 Elsevier B.V. All rights reserved.