Effect of pressure on hydrogen bonding in liquid methanol -: art. no. 195504

被引：48

作者：

Arencibia, A ^{[1
]}

Taravillo, M ^{[1
]}

Pérez, FJ ^{[1
]}

Núñez, J ^{[1
]}

Baonza, VG ^{[1
]}

机构：

[1] Univ Complutense Madrid, Fac Ciencias Quim, Dept Quim Fis 1, E-28040 Madrid, Spain

来源：

PHYSICAL REVIEW LETTERS | 2002年 / 89卷 / 19期

关键词：

D O I：

10.1103/PhysRevLett.89.195504

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

We have investigated the effect of pressure on the hydrogen bonding in liquid methanol using Raman spectroscopy. Specifically, we have measured the OH and CO stretching modes and assigned the bands, in agreement with recent IR and crossed molecular beam experiments on methanol clusters. At about 7 to 8 kbar, we note indications that the intrinsic nature of the methanol clusters in our samples has changed. Our results provide support for and extend conclusions derived from Monte Carlo simulations, explain anomalies observed by previous researchers, and provide new insights into general hydrogen-bonding phenomena.

引用

页数：4

共 34 条

[1]

[Anonymous], 2021, METASTABLE LIQUIDS

[2] Molecular clusters in liquid methanol:: a Reverse Monte Carlo study [J].

Bakó, I ;

Jedlovszky, P ;

Pálinkás, G .

JOURNAL OF MOLECULAR LIQUIDS, 2000, 87 (2-3) :243-254

[3] High pressure chemistry of molecular systems: Recent experimental results and developments [J].

Baonza, VG .

HIGH PRESSURE RESEARCH, 2000, 18 (1-6) :379-389

[4] LOW-TEMPERATURE INFRARED STUDY OF STERICALLY HINDERED ASSOCIATED ALCOHOLS [J].

BOURDERON, C ;

SANDORFY, C ;

PERON, JJ .

JOURNAL OF PHYSICAL CHEMISTRY, 1972, 76 (06) :864-+

[5] Water, in the liquid and five solid forms, under pressure [J].

Bridgman, PW .

PROCEEDINGS OF THE AMERICAN ACADEMY OF ARTS AND SCIENCES, 1912, 47 (13/22) :441-558

[6] Structure and vibrational spectra of methanol clusters from a new potential model [J].

Buck, U ;

Siebers, JG ;

Wheatley, RJ .

JOURNAL OF CHEMICAL PHYSICS, 1998, 108 (01) :20-32

[7] INFRARED PHOTODISSOCIATION OF SIZE-SELECTED METHANOL CLUSTERS [J].

BUCK, U ;

GU, XJ ;

LAUENSTEIN, C ;

RUDOLPH, A .

JOURNAL OF CHEMICAL PHYSICS, 1990, 92 (10) :6017-6029

[8] The effect of high pressure on the near infrared absorption spectrum of certain liquids [J].

Collins, JR .

PHYSICAL REVIEW, 1930, 36 (02) :0305-0310

[9] Pressure and temperature dependence of hydrogen-bond strength in methanol clusters [J].

Czeslik, C ;

Jonas, J .

CHEMICAL PHYSICS LETTERS, 1999, 302 (5-6) :633-638

[10] Pressure dependent vibrational Fermi resonance in liquid CH3OH and CH2Cl2 [J].

Devendorf, GS ;

Hu, MHA ;

Ben-Amotz, D .

JOURNAL OF PHYSICAL CHEMISTRY A, 1998, 102 (52) :10614-10619

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